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ChemistryChemistry & Chemical ReactivityWe know that the decomposition of SO 2 Cl 2 is first-order in SO 2 Cl 2 , SO 2 Cl 2 → SO 2 (g) + Cl 2 (g) with a half-life of 245 minutes at 600 K. If you begin with a partial pressure of SO 2 Cl 2 of 25 mm Hg in a 1.0-L flask what is the partial pressure of each reactant and product after 245 minutes? What is the partial pressure of each reactant and product after 12 hours?
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We know that the decomposition of SO 2 Cl 2 is first-order in SO 2 Cl 2 , SO 2 Cl 2 → SO 2 (g) + Cl 2 (g) with a half-life of 245 minutes at 600 K. If you begin with a partial pressure of SO 2 Cl 2 of 25 mm Hg in a 1.0-L flask what is the partial pressure of each reactant and product after 245 minutes? What is the partial pressure of each reactant and product after 12 hours?

BuyFind

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074
BuyFind

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074

Solutions

Chapter
Section
Problem 1PS
Problem 2PS
Problem 3PS
Problem 4PS
Problem 5PS
Problem 6PS
Problem 7PS
Problem 8PS
Problem 9PS
Problem 10PS
Problem 11PS
Problem 12PS
Problem 13PS
Problem 14PS
Problem 15PS
Problem 16PS
Problem 17PS
Problem 18PS
Problem 19PS
Problem 20PS
Problem 21PS
Problem 22PS
Problem 23PS
Problem 24PS
Problem 25PS
Problem 26PS
Problem 27PS
Problem 28PS
Problem 29PS
Problem 30PS
Problem 31PS
Problem 32PS
Problem 33PS
Problem 34PS
Problem 35PS
Problem 36PS
Problem 37PS
Problem 38PS
Problem 39PS
Problem 40PS
Problem 41PS
Problem 42PS
Problem 43PS
Problem 44PS
Problem 45PS
Problem 46PS
Problem 47PS
Problem 48PS
Problem 49PS
Problem 50PS
Problem 51PS
Problem 52PS
Problem 53GQ
Problem 54GQ
Problem 55GQ
Problem 56GQ
Problem 57GQ
Problem 58GQ
Problem 59GQ
Problem 60GQ
Problem 61GQ
Problem 62GQ
Problem 63GQ
Problem 64GQ
Problem 65GQ
Problem 66GQ
Problem 67GQ
Problem 68GQ
Problem 69GQ
Problem 70GQ
Problem 71GQ
Problem 72GQ
Problem 73GQ
Problem 74GQ
Problem 75GQ
Problem 76GQ
Problem 77GQ
Problem 78GQ
Problem 79GQ
Problem 80GQ
Problem 81GQ
Problem 82GQ
Problem 83GQ
Problem 84GQ
Problem 85IL
Problem 87IL
Problem 88IL
Problem 89IL
Problem 90IL
Problem 91SCQ
Problem 93SCQ
Problem 94SCQ
Problem 95SCQ
Problem 96SCQ
Problem 97SCQ
Problem 98SCQ
Problem 99SCQ
Problem 100SCQ
Problem 101SCQ
Chapter 14, Problem 82GQ
Textbook Problem

We know that the decomposition of SO2Cl2 is first-order in SO2Cl2,

SO2Cl2 → SO2(g) + Cl2(g)

with a half-life of 245 minutes at 600 K. If you begin with a partial pressure of SO2Cl2 of 25 mm Hg in a 1.0-L flask what is the partial pressure of each reactant and product after 245 minutes? What is the partial pressure of each reactant and product after 12 hours?

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Chapter 14,
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Chapter 14 Solutions

Chemistry & Chemical Reactivity
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Ch. 14.1 - Sucrose decomposes to fructose and glucose in acid...Ch. 14.1 - What are the relative rates of appearance or...Ch. 14.3 - The initial rate ( [NO]/ t] of the reaction of...Ch. 14.3 - The rate constant, k, at 25 C is 0.27/h for the...Ch. 14.4 - Sucrose, a sugar, decomposes in acid solution to...Ch. 14.4 - Gaseous azomethane (CH3N2CH3) decomposes to ethane...Ch. 14.4 - Using the rate constant for HI decomposition given...Ch. 14.4 - The catalyzed decomposition of hydrogen peroxide...Ch. 14.4 - Americium is used in smoke detectors and in...Ch. 14.5 - Rate constants were determined for the...Ch. 14.5 - The colorless gas N2O4, decomposes to the brown...Ch. 14.7 - Nitrogen monoxide is reduced by hydrogen to give...Ch. 14.7 - The Raschig reaction produces hydrazine, N2H4, an...Ch. 14.7 - One possible mechanism for the decomposition of...Ch. 14.7 - Catalase can decompose hydrogen peroxide to O2 and...Ch. 14.7 - How many moles of carbonic anhydrase (approximate...Ch. 14.7 - Sullivan used 578-nm light to dissociate I2...Ch. 14.7 - Show that the two step mechanism proposed by...Ch. 14.7 - Why is a termolecular elementary step likely to be...Ch. 14.7 - Determine the activation energy for the reaction...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - In the reaction 2 O3(g) 3 O2(g), the rate of...Ch. 14 - In the synthesis of ammonia, if [H2]/t = 4.5 104...Ch. 14 - Experimental data are listed here for the reaction...Ch. 14 - Phenyl acetate, an ester, reacts with water...Ch. 14 - Using the rate equation Rate = k[A]2[B], define...Ch. 14 - A reaction has the experimental rate equation Rate...Ch. 14 - The reaction between ozone and nitrogen dioxide at...Ch. 14 - Nitrosyl bromide, NOBr, is formed from NO and Br2:...Ch. 14 - The data in the table are for the reaction of NO...Ch. 14 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 14 - Data for the reaction NO(g) + O2(g) NO2(g) are...Ch. 14 - Data for the following reaction are given in the...Ch. 14 - The rate equation for the hydrolysis of sucrose to...Ch. 14 - The decomposition of N2O5 in CCl4 is a first-order...Ch. 14 - The decomposition of SO2Cl2 is a first-order...Ch. 14 - The conversion of cyclopropane to propene (Example...Ch. 14 - Hydrogen peroxide, H2O2(aq), decomposes to H2O()...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - At 573 K, gaseous NO2(g) decomposes, forming NO(g)...Ch. 14 - The dimerization of butadiene, C4H6, to form...Ch. 14 - The decomposition of ammonia on a metal surface to...Ch. 14 - Hydrogen iodide decomposes when heated, forming...Ch. 14 - The rate equation for the decomposition of N2O5...Ch. 14 - Gaseous azomethane, CH3N=NCH3, decomposes in a...Ch. 14 - The decomposition of SO2Cl2 SO2Cl2(g) SO2(g) +...Ch. 14 - The compound Xe(CF3)2 decomposes in a first-order...Ch. 14 - The radioactive isotope 64Cu is used in the form...Ch. 14 - Radioactive gold-198 is used in the diagnosis of...Ch. 14 - Data for the decomposition of dinitrogen monoxide...Ch. 14 - Ammonia decomposes when heated according to the...Ch. 14 - Gaseous NO2 decomposes at 573 K. NO2(g) NO(g) + ...Ch. 14 - The decomposition of HOF occurs at 25 C. HOF(g) ...Ch. 14 - For the reaction C2F4 C4F8, a graph of 1/[C2F4]...Ch. 14 - Butadiene, C4H6(g), dimerizes when heated, forming...Ch. 14 - Calculate the activation energy, Ea, for the...Ch. 14 - If the rate constant for a reaction triples when...Ch. 14 - When healed lo a high temperature, cyclobutane,...Ch. 14 - When heated, cyclopropane is converted to propene...Ch. 14 - The reaction of H2 molecules with F atoms H2(g) +...Ch. 14 - Answer the following questions based on the...Ch. 14 - Compare the lock-and-key and induced-fit models...Ch. 14 - To which species should an enzyme bind best: the...Ch. 14 - According to the Michaelis-Menten model, if 1/Rate...Ch. 14 - The enzyme carbonic anhydrase catalyzes the...Ch. 14 - What is the rate law for each of the following...Ch. 14 - What is the rate law for each of the following...Ch. 14 - Ozone, O3, in the Earths upper atmosphere...Ch. 14 - The reaction of NO2(g) and CO(g) is thought to...Ch. 14 - A proposed mechanism for the reaction of NO2 and...Ch. 14 - The mechanism for the reaction of CH3OH and HBr is...Ch. 14 - A reaction has the following experimental rate...Ch. 14 - For a first-order reaction, what fraction of...Ch. 14 - To determine the concentration dependence of the...Ch. 14 - Data for the following reaction are given in the...Ch. 14 - Formic acid decomposes at 550 C according to the...Ch. 14 - Isomerization of CH3NC occurs slowly when CH3NC is...Ch. 14 - When heated, tetrafluoroethylene dimerizes to form...Ch. 14 - Data in the table were collected at 540 K for the...Ch. 14 - Ammonium cyanate, NH4NCO, rearranges in water to...Ch. 14 - NOx, mixture of NO and NO2, plays an essential...Ch. 14 - At temperatures below 500 K, the reaction between...Ch. 14 - Nitryl fluoride can be made by treating nitrogen...Ch. 14 - The decomposition of dinitrogen pentaoxide N2O5(g)...Ch. 14 - The data in the table give the temperature...Ch. 14 - The decomposition of gaseous dimethyl ether at...Ch. 14 - The decomposition of phosphine, PH3, proceeds...Ch. 14 - The thermal decomposition of diacetylene, C4H2,...Ch. 14 - Kinetic experiments were conducted to determine...Ch. 14 - The ozone in the Earths ozone layer decomposes...Ch. 14 - Hundreds of different reactions occur in the...Ch. 14 - Data for the reaction [Mn(CO)5(CH3CN)]+ + NC5H5 ...Ch. 14 - The gas-phase reaction 2 N2O5(g) 4 NO2(g) + O2(g)...Ch. 14 - A reaction that occurs in our atmosphere is the...Ch. 14 - The decomposition of SO2Cl2 to SO2 and Cl2 is...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - Hydrogen peroxide, H2O2(aq), decomposes to H2O()...Ch. 14 - Egg protein albumin is precipitated when an egg is...Ch. 14 - A The compound 1,3-butadiene (C4H6) forms...Ch. 14 - Hypofluorous acid, HOF, is very unstable,...Ch. 14 - We know that the decomposition of SO2Cl2 is...Ch. 14 - Nitramide, NO2NH2, decomposes slowly in aqueous...Ch. 14 - Many biochemical reactions are catalyzed by acids....Ch. 14 - The color change accompanying the reaction of...Ch. 14 - The enzyme chymotrypsin catalyzes the hydrolysis...Ch. 14 - The substitution of CO in Ni(CO)4 by another...Ch. 14 - The oxidation of iodide ion by the hypochlorite...Ch. 14 - The acid-catalyzed iodination of acetone...Ch. 14 - Hydrogenation reactions, processes wherein H2 is...Ch. 14 - The following statements relate to the reaction...Ch. 14 - Chlorine atoms contribute to the destruction of...Ch. 14 - Describe each of the following statements as true...Ch. 14 - Identify which of the following statements are...Ch. 14 - The reaction cyclopropane propene occurs on a...Ch. 14 - Isotopes are often used as tracers to follow an...Ch. 14 - Examine the reaction coordinate diagram given...Ch. 14 - Draw a reaction coordinate diagram for an...Ch. 14 - Consider the reaction of ozone and nitrogen...

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