(a) Interpretation: The curved-arrow mechanism for the hydrolysis of the N -methylbenzamide in acidic solution is to be stated. Concept introduction: The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 1

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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(b) Suggest a reasonable biosynthesis for the naturally occurring alkaloid coniine (isolated from hemlock), starting from octanoic acid. Coniine

(a) Account for the following :(i) Propanal is more reactive than propanone towards nucleophilic reagents.(ii) Electrophilic substitution in benzoic acid takes place at meta position.(iii) Carboxylic acids do not give characteristic reactions of carbonyl group.(b) Give simple chemical test to distinguish between the following pairs of compounds:(i) Acetophenone and benzaldehyde(ii) Benzoic acid and ethylbenzoate.

(a) Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two reasons.(b) How will you bring about the following converstions?(i) Propanone to propane (ii) Benzoyl chloride to benzaldehyde(iii) Ethanal to but-2-enal

Answer 2

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 3

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 4

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 5

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 6

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 7

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains the curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution.

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Chapter 21 Solutions