(a) Interpretation: Whether the conformation of the given structure of N − acetylproline is E or Z is to be stated. Concept introduction: E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

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Answer 1

Question

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

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'' Which of the statements A-E is NOT correct about azidothymidine (AZT), an antiviral drug? (a) The molecule contains a sigma bond formed by the overlap of a nitrogen sp orbital with a nitrogen sp2 H3C. NH orbital (b) It contains a secondary (2°) amine (c) It contains a primary (1°) alcohol (d) The molecule contains the following functional groups: alkene, amide, ether (e) It contains one atom with a +1 formal charge and one with a -1 formal charge HOH2C N=N=N

Which of the statements A-E is NOT correct about azidothymidine 18) (AZT), an antiviral drug? (a) The molecule contains a sigma bond formed by the overlap of a nitrogen sp orbital with a nitrogen sp? H3C. NH orbital (b) It contains a secondary (2°) amine (c) It contains a primary (1°) alcohol (d) The molecule contains the following functional groups: alkene, amide, ether (e) It contains one atom with a +1 formal charge and one with a -1 formal charge HOH2C- N=N=N

Answer 2

Question

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

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Answer 3

Question

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

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Answer 4

Question

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

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Answer 5

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Answer 6

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Answer 7

Chapter 21, Problem 21.3P

Interpretation Introduction

(a)

Interpretation:

Whether the conformation of the given structure of N−acetylproline is E or Z is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of other conformation is to be stated.

Concept introduction:

E or Z configuration is dependent on the atomic number of the atoms attached to the double bond. If the higher priority atoms are present on the same side of the double bond, then it is assigned as Z configuration. If the higher priority atoms present on the opposite side of the double bond then it is assigned as E configuration.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains that the conformation of the given structure of N-acetylproline is E or Z configuration.

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Chapter 21 Solutions