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(a)
Interpretation:
The mechanism for the formation of the by-product obtained in the reaction
Concept introduction:
The
(b)
Interpretation:
The reason as to why ammonia added to the reaction mixture prevents the formation of by-product is to be stated.
Concept introduction:
The chemical reaction in which hydrogen molecule is used in the presence of nickel as a catalyst to reduce an organic compound is known as hydrogenation reaction. Hydrogenation is basically used to add the pair of hydrogen atoms to an alkene.
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Chapter 21 Solutions
EBK ORGANIC CHEMISTRY
- Name (by the common system of nomenclature) the amine (or ammonia) that is formed by the basic hydrolysis of the following acid amide: 01C NH₂arrow_forwardGive at least 5 examples of biological compounds having an amine functional group and identify the biochemical importance of each compound.arrow_forwardTRUE OR FALSE (a) There are three amines with the molecular formula C3H9N. (b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (f) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forward
- Is N-methylaminobenzoic acid a primary aminearrow_forwardIndicate the category of base to which the following compound belongs: Сасоз Hydride Amine O Carbonate O Bicarbonate Hydroxide Alkoxide O Carbanion O Amidearrow_forwardWrite the chemical equation for the acid dissociation of acetaminophen, C8H9O2N. Write the Ka expression for the acid dissociation of acetaminophen.arrow_forward
- (a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.arrow_forwardCalculate the maximum number of possible stereoisomers of 2-methylocta-4,6-1-amine using the following formula: Maximum number of possible stereoisomers = 2n (where n= the number of chiral carbons in your molecule). This calculation does not include E- or Z- isomers for any compounds containing double bondsarrow_forwardDraw a structure for the product formed in this reductive amination reaction. Upload a jpg image of your answer showing the full reaction (not just the product). + HN NaBH₂CN, EtOH, pH= 4arrow_forward
- Classify the following compounds as primary (1o), secondary (2o), or tertiary (3o) amines:arrow_forwardThree amide isomers, N,N-dimethylformamide, N-methylacetamide, and propanamide, have respective boiling points of 153 °C (426 K), 202 °C (475 K), and 213 °C (486 K). Explain these boiling points in light of their structural formulas.arrow_forwardGive the IUPAC name of the following compound:arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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