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(a)
Interpretation:
The sequence of reaction for the conversion of benzoic acid to
Concept introduction:
Organic or inorganic reagents are used for the synthesis of required compounds. There are various reagents used for the analysis of the compounds and for the conversion of one compound into another. Grignard reagents are
(b)
Interpretation:
The sequence of reaction for the conversion of butyric acid to
Concept introduction:
Organic or inorganic reagents are used for the synthesis of required compounds. There are various reagents used for the analysis of the compounds and for the conversion of one compound into another. Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.
(c)
Interpretation:
The sequence of reaction for the conversion of isobutyronitrile to
Concept introduction:
Organic or inorganic reagents are used for the synthesis of required compounds. There are various reagents used for the analysis of the compounds and for the conversion of one compound into another. Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.
(d)
Interpretation:
The sequence of reaction for the conversion of propionic acid to
Concept introduction:
Organic or inorganic reagents are used for the synthesis of required compounds. There are various reagents used for the analysis of the compounds and for the conversion of one compound into another. Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.
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Chapter 21 Solutions
EBK ORGANIC CHEMISTRY
- a) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forwardb) Compounds in which the –OH of the carboxyl group is replaced by certain other groups are called carboxylic acid derivatives. The most important of which are acyl halides, acid anhydrides, esters and amides. Discuss the relationship between carboxylic acid, acid chloride and acid anhydridearrow_forwarda) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forward
- Complete the following reactions and hence identify the nature of the acid-base interaction and the name associated with acid-base interaction that you have chosen. Q1. (a) H30* + OH >arrow_forward(a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.arrow_forwardMethyllithium (CH3Li) is often used as a base in organic reactions. Predict the products of the following acid-base reaction.CH3CH2¬OH + CH3¬Li ¡arrow_forward
- Using the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forwardPhotochemical chlorination of 2,2,4-trimethylpentane gives four isomeric monochlorides. (a) Write structural formulas for these four isomers. (b) The two primary chlorides make up 65% of the monochloride fraction. Assuming that all the primary hydrogens in 2,2,4-trimethylpentane are equally reactive, estimate the percentage of each of the two primary chlorides in the product mixture.arrow_forwardWrite equations to show how the following compounds are oxidized by (1) K2Cr2O7 + H2SO4, (2) Cu2+, or Ag+: (a) 1-propanol (b) 2,3-dimethyl-2-butanolarrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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