The Science and Engineering of Materials (MindTap Course List)
7th Edition
ISBN: 9781305076761
Author: Donald R. Askeland, Wendelin J. Wright
Publisher: Cengage Learning
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Chapter 5, Problem 5.29P
To determine
The diffusion coefficient for the diffusion of hydrogen through BCC iron and FCC aluminium. The better suited material for a high pressure hydrogen storage tank.
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Rank the magnitudes of the diffusion coefficients from greatest to least for the following systems:
N in Fe at 700°C
Cr in Fe at 700°C
N in Fe at 900°C
Cr in Fe at 900°C
Now justify this ranking. (Note: Both Fe and Cr have the BCC crystal structure, and the atomic radii for Fe, Cr, and N are 0.124, 0.125, and 0.065 nm, respectively. You may also want to refer to Section 5.4.)
Calculate the value of the diffusion coefficient D (in m^2/s) at 694°C for the diffusion of some species in a metal; assume that the values of D0 and Qd are 5.6 x 10^-5 m^2/s and 177 kJ/mol, respectively. R=8.314 J/(mol*K)
The diffusion coefficients for species A in metal B are given at two temperatures:
D (m²/s)
7.81 x 10-17
7.70x 10-16
i
(b) Determine the value of Do.
(a) Determine the value of the activation energy Qd (in J/mol).
i
T (°C)
1030
i
1260
J/mol
m²/s (Use scientific notation.)
(c) What is the magnitude of D at 1180°C?
m²/s (Use scientific notation.)
Chapter 5 Solutions
The Science and Engineering of Materials (MindTap Course List)
Ch. 5 - What is the driving force for diffusion?Ch. 5 - Give three examples of materials processes that...Ch. 5 - In the carburization treatment of steels, what are...Ch. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - A certain mechanical component is heat treated...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Compare the diffusion coefficients of carb on in...Ch. 5 - Prob. 5.18PCh. 5 - Activation energy is sometimes expressed as...Ch. 5 - Prob. 5.20PCh. 5 - The activation energy for the diffusion of copper...Ch. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Write down Fick’s first law of diffusion. Clearly...Ch. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - A 1-mm-thick BCC iron foil is used to separate a...Ch. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - A 0.001 in. BCC iron foil is used to separate a...Ch. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Pure zinc is to be diffused into copper by dipping...Ch. 5 - Nitriding is a process in which nitrogen is...Ch. 5 - Determine the carburizing time necessary to...Ch. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Compare the rate at which oxygen ions diffuse in...Ch. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - A 0.80% C steel must operate at 950°C in an...Ch. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Most metals and alloys can be processed using the...Ch. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - A ceramic part made from MgO is sintered...Ch. 5 - Prob. 5.78PCh. 5 - What are the advantages of using hot pressing and...Ch. 5 - Prob. 5.80PCh. 5 - Prob. 5.81DPCh. 5 - Design a spherical tank, with a will thickness of...Ch. 5 - Prob. 5.83DPCh. 5 - Prob. 5.84DPCh. 5 - Prob. 5.85DPCh. 5 - Prob. 5.86CPCh. 5 - Prob. 5.87CPCh. 5 - Prob. 5.88CPCh. 5 - Prob. 5.1KP
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