The Science and Engineering of Materials (MindTap Course List)
7th Edition
ISBN: 9781305076761
Author: Donald R. Askeland, Wendelin J. Wright
Publisher: Cengage Learning
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Question
Chapter 5, Problem 5.54P
To determine
The concentration of nitrogen at a given location and temperature.
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A mechanism for hardening steel is called carburization. To achieve this process, the piece of steel is exposed to an atmosphere rich in hydrocarbon such as methane (CH4). Consider a steel with a carbide concentration of 0.25wt%, which must be treated at 950˚C. If the carbon concentration at the surface is suddenly increased to 1.20wt%, how long does it take for a penetration of 0.5mm from the surface to reach a concentration of 0.80wt%? . The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2s-1. Assume that the piece of steel is semi-finite. Use the table below.
6. (20%) Pure zinc is to be diffused into the copper by dipping copper into molten zinc at 450°C. Calculate how long would take to obtain 10wt% zinc at a depth of 0.5 mm beneath the copper surface. Is this commercially feasible? What practical problems might arise if we raise the temperature to 1000°C ? Use Table below for error function values as needed. At 450°C, the diffusion coefficient D = 6.3 10-17 m²/s.
d. An Aluminum-Copper alloy initially containing (0.4 wt% Cu) is
placed and held in an atmosphere that gives a constant surface
Aluminum concentration of (1.0 wt% ). If after (43 h) the
concentration of copper is (0.55 wt%) at a position (4.0 mm) below
the surface. What is the diffusion coefficient of copper in
aluminum for the treatment conditions.
z
erf(z)
0.6778
0.70
0.75
0.7112
0.80
0.7421
0.85
0.7707
0.90
0.7970
Chapter 5 Solutions
The Science and Engineering of Materials (MindTap Course List)
Ch. 5 - What is the driving force for diffusion?Ch. 5 - Give three examples of materials processes that...Ch. 5 - In the carburization treatment of steels, what are...Ch. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - A certain mechanical component is heat treated...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Compare the diffusion coefficients of carb on in...Ch. 5 - Prob. 5.18PCh. 5 - Activation energy is sometimes expressed as...Ch. 5 - Prob. 5.20PCh. 5 - The activation energy for the diffusion of copper...Ch. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Write down Fick’s first law of diffusion. Clearly...Ch. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - A 1-mm-thick BCC iron foil is used to separate a...Ch. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - A 0.001 in. BCC iron foil is used to separate a...Ch. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Pure zinc is to be diffused into copper by dipping...Ch. 5 - Nitriding is a process in which nitrogen is...Ch. 5 - Determine the carburizing time necessary to...Ch. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Compare the rate at which oxygen ions diffuse in...Ch. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - A 0.80% C steel must operate at 950°C in an...Ch. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Most metals and alloys can be processed using the...Ch. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - A ceramic part made from MgO is sintered...Ch. 5 - Prob. 5.78PCh. 5 - What are the advantages of using hot pressing and...Ch. 5 - Prob. 5.80PCh. 5 - Prob. 5.81DPCh. 5 - Design a spherical tank, with a will thickness of...Ch. 5 - Prob. 5.83DPCh. 5 - Prob. 5.84DPCh. 5 - Prob. 5.85DPCh. 5 - Prob. 5.86CPCh. 5 - Prob. 5.87CPCh. 5 - Prob. 5.88CPCh. 5 - Prob. 5.1KP
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- 3. A BCC iron alloy containing 0.05 wt% C is carburized at 1050°C such that the carbon concentration is 0.5 wt% at a distance 2mm from the surface. Meanwhile, the carbon concentration at the surface is kept constant at 1.5 wt% C. a. What is the value of the diffusion constant for carbon diffusing into BCC Fe at 1050 °C? Show all work. Write the relevant equation for the diffusivity within this box: Write the values of all of the parameters in the equation above within the box below: Write your final answer for the diffusivity within this box: b. Determine the diffusion time required to achieve the carbon profile described above. Show all work. Write the relevant equation needed to solve this problem within this box: Write the values of all of the given parameters in the equation above within the box below: Write the value for erf(z) within this box:arrow_forwardYou want to carburize a steel drill bit in the presence of methane. The drill bit initially has a uniform carbon concentration of 0.25 wt% and is to be treated at 950 oC (1750 oF). If the concentration of carbon at the surface is suddenly brought to and maintained at 1.20 wt%, how long will it take to achieve a carbon content of 0.80 wt% at a position 0.5mm below the surface? (The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2/s.)arrow_forwardAn FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere wherein the surface carbon concentration is maintained at 1.0 wt%. If after 51 h the concentration of carbon is 0.35 wt% at a position 3.5 mm below the surface, determine the temperature at which the treatment was carried out. You will need to use data in the two tables below to solve this problem. Diffusing Species Fe Table 5.1 Tabulation of Error Function Values erf(z) 0 0.0282 0.0564 0.1125 Fe Z 0 0.025 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 Table 5.2 A Tabulation of Diffusion Data Host Metal a-Fe (BCC) y-Fe (FCC) a-Fe 0.1680 0.2227 0.2763 0.3286 0.3794 y-Fe 0.4284 0.4755 0.5205 Z 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.0 1.1 1.2 Do(m²/s) 2.8 x 10-4 5.0 x 10-5 6.2 x 10-7 2.3 x 10-5 erf(z) 0.5633 0.6039 0.6420 0.6778 0.7112 0.7421 0.7707 0.7970 0.8209 0.8427 0.8802 0.9103 80 284 Z 1.3 1.4 1.5 1.6 1.7 1.8 1.9 Activation Energy Qa kJ/mol eVlatom 251…arrow_forward
- (c) Consider an alloy that is undergoing carburizing process, initially has a uniform carbon concentration of 0.27 wt% and is to be treated at 950oC (1750oF). If the concentration of carbon at the surface is suddenly brought to and maintained at 1.32 wt%, how long will it take to achieve a carbon content of 0.85% at a position 0.7 mm below the surface? The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2/s; assume that the steel piece is semi-finite.arrow_forwardDecarburization of a steel occurs when carbon diffuses from the steel to the surface and enters the atmosphere. How long will it take for a 0.6 % C steel surface to decarburize below 0.1 % C for a depth of 2 mm if the FCC steel is held at 1250 °C in an atmosphere containing zero carbon? I need this question's answer. It's important for me.arrow_forwardCompare the diffusion coefficients (in cm²/s) of nitrogen in BCC and FCC iron at the allotropic transformation temperature of 912°C. Decc -153606 X Your response differs from the correct answer by more than 10%. Double check your calculations, cm²/s -1976-7 Dicc x Your response differs significantly from the correct answer. Rework your solution from the beginning and check each step carefully. cm2/sarrow_forward
- 1. An FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere that gives a surface carbon concentration constant at 1.0 wt%. If after 49.5 h, the concentration of carbon is 0.35 wt% at a position 4.0 mm below the surface, determine the temperature at which the treatment was carried out. 2. Consider a metal single-crystal oriented such that the normal to the slip plane and the slip direction are at angles of 60° and 35°, respectively, with the tensile axis. If the critical resolved shear stress is 20.7 MPa, will an applied stress of 45 MPa cause the single crystal to yield? If not, what stress will be necessary?arrow_forwardAn FCC iron-carbon alloy initially containing 0.10 wt% C is carburized at an elevated temperature and in an atmosphere in which the surface carbon concentration is maintained at 1.10 wt%. If the treatment is conducted at 1050 °C, how long should the treatment be performed to reach a 0.30 wt% of carbon concentration at a position 4.2 mm below the surface?arrow_forward(c) A 1020 steel gear is carburized at 927°C and gives the surface carbon concentration maintained at 1.2 wt%. After 8 hours, the concentration of carbon is 0.4 wt%. Note: D (C in y iron) at 927°C = 1.28 × 10*1" m²/s. Determine the depth of the carbon diffuse to the gear steel after 8 hours. (d) State the importance of case hardening in gear steel components in the steel metal industry.arrow_forward
- QUESTION 7 .An experiment is conducted to determine the variation of the diffusion coefficient as a function of temperature when carbon is diffused into BCC iron. The diffusion coefficient is measured at two different temperatures and is given by: Temp (°C) D (m2/s) 100 6.2 x 10-12 542 3.1 x 10-10 Calculate a value for the activation energy Qd (eV/atom) based on the experimental data?arrow_forwardDiffusion of carbon into BCC iron for 12 hours at a temperature of 500 °C results in a carbon concentration of 0.2 wt% at a depth 2 mm from the surface. How long would it take to get a concentration of 0.2 wt% at a depth 3 mm from the surface at 500 °C?arrow_forwardPlease kindly help. I will give a like. Thank you! a. Describe the S-curve model of diffusion on how does ‘rate of adoption’ change over time? At which-point is the rate of diffusion the fastest? b. S-curve model of diffusion: (true/false) and reasoning - k = 0, the rate of diffusion is instantaneous? - fixed k ≥ 0, the carrying capacity is determined only by the ratio of a and b? - fixed k ≥ 0, the rate of diffusion is determined only by the ratio of a and b? c. The diffusion of hybrid corn in the 1940s, who or which region seems to have adopted the hybrids more quickly and why?arrow_forward
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