The Science and Engineering of Materials (MindTap Course List)
7th Edition
ISBN: 9781305076761
Author: Donald R. Askeland, Wendelin J. Wright
Publisher: Cengage Learning
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Chapter 5, Problem 5.67P
To determine
The nitrogen content at 0.25 mm from the surface.
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Determine the carburizing time necessary to achieve a carbon concentration of 0.50 wt% at a position 3.1 mm into an iron-carbon
alloy that initially contains 0.12 wt% C. The surface concentration is to be maintained at 1.2 wt% C, and the treatment is to be
conducted at 1080°C. Assume that Do = 5.8 x 10-5 m²/s and Qd = 156 kJ/mol. The table Tabulation Error Function Values may be
useful.
A mechanism for hardening steel is called carburization. To achieve this process, the piece of steel is exposed to an atmosphere rich in hydrocarbon such as methane (CH4). Consider a steel with a carbide concentration of 0.25wt%, which must be treated at 950˚C. If the carbon concentration at the surface is suddenly increased to 1.20wt%, how long does it take for a penetration of 0.5mm from the surface to reach a concentration of 0.80wt%? . The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2s-1. Assume that the piece of steel is semi-finite. Use the table below.
A 1020 steel contains 0.20% carbon is carburized by a source that maintains a surface carbon content 0f
2.0% C. It is desired to produce a 0.80 wt% C concentration 0.1 cm below the steel surface after a 4-hour
treatment. At what temperature should the carburization be carried out? R = 8.314 J/mol•K; DO =
2.3x10-5 m2 /s; Qd=148,000 J/mol
erf(z)
erf(z)
erf(z)
0.55
0.5633
1.3
0.9340
0.025
0.05
0.0282
0.60
0.6039
1.4
0.9523
0.0564
0.65
0.6420
1.5
0.9661
0.10
0.1125
0.70
0.6778
1.6
0.9763
0.15
0.1680
0.75
0.7112
1.7
0.9838
0.20
0.25
0.30
0.2227
0.80
0.7421
1.8
0.9891
0.2763
0.85
0.7707
1.9
0.9928
0.3286
0.90
0.7970
2.0
0.9953
0.35
0.3794
0.95
0.8209
2.2
0.9981
0.40
0.4284
1.0
0.8427
2.4
0.9993
0.45
0.4755
1.1
0.8802
2.6
0.9998
0.50
0.5205
1.2
0.9103
2.8
0.9999
Chapter 5 Solutions
The Science and Engineering of Materials (MindTap Course List)
Ch. 5 - What is the driving force for diffusion?Ch. 5 - Give three examples of materials processes that...Ch. 5 - In the carburization treatment of steels, what are...Ch. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - A certain mechanical component is heat treated...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Compare the diffusion coefficients of carb on in...Ch. 5 - Prob. 5.18PCh. 5 - Activation energy is sometimes expressed as...Ch. 5 - Prob. 5.20PCh. 5 - The activation energy for the diffusion of copper...Ch. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Write down Fick’s first law of diffusion. Clearly...Ch. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - A 1-mm-thick BCC iron foil is used to separate a...Ch. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - A 0.001 in. BCC iron foil is used to separate a...Ch. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Pure zinc is to be diffused into copper by dipping...Ch. 5 - Nitriding is a process in which nitrogen is...Ch. 5 - Determine the carburizing time necessary to...Ch. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Compare the rate at which oxygen ions diffuse in...Ch. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - A 0.80% C steel must operate at 950°C in an...Ch. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Most metals and alloys can be processed using the...Ch. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - A ceramic part made from MgO is sintered...Ch. 5 - Prob. 5.78PCh. 5 - What are the advantages of using hot pressing and...Ch. 5 - Prob. 5.80PCh. 5 - Prob. 5.81DPCh. 5 - Design a spherical tank, with a will thickness of...Ch. 5 - Prob. 5.83DPCh. 5 - Prob. 5.84DPCh. 5 - Prob. 5.85DPCh. 5 - Prob. 5.86CPCh. 5 - Prob. 5.87CPCh. 5 - Prob. 5.88CPCh. 5 - Prob. 5.1KP
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- Problem 2 Determine the carburizing time necessary to achieve a carbon concentration of 0.45 wt% at a position 2 mm into an iron-carbon alloy that initially contains 0.20 wt% C. The surface concentration is to be maintained at 1.30 wt% C, and the treatment is to be conducted at 1000 °C. Use the diffusion data for y-Fe in Table 5.2.arrow_forwardDuring freezing of a Cu-Zn alloy, we find that the composition is non-uniform. By heating the alloy to 600°C for 3 hours, diffusion of zinc helps to make the composition more uniform. What temperature would be required if we wished to perform this homogenization treatment in 30 minutes?arrow_forward•You are case-hardening a tool made of BCC (α) iron in the presence of a carbonaceous material. A heat treatment at 600 oC for 100 minutes results in a carbon concentration of 0.75 wt% at a position 0.5mm below the surface. How long would it take to obtain the same concentration at the same position if the heat treatment were conducted at 900 oC? x12/D1t1= x22/D2t2 Arrhenius equation: D=D0e^(〖-Qd〗∕RT) Qd = Activation energy of diffusion D0 = Pre-exponential diffusion factor R = gas constant = 8.314 J/(mol*K) Use the Arrhenius equation to calculate D1 and D2. Calculate the time to satisfy the problem statement.arrow_forward
- 1. An FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere that gives a surface carbon concentration constant at 1.0 wt%. If after 49.5 h, the concentration of carbon is 0.35 wt% at a position 4.0 mm below the surface, determine the temperature at which the treatment was carried out. 2. Consider a metal single-crystal oriented such that the normal to the slip plane and the slip direction are at angles of 60° and 35°, respectively, with the tensile axis. If the critical resolved shear stress is 20.7 MPa, will an applied stress of 45 MPa cause the single crystal to yield? If not, what stress will be necessary?arrow_forwardMaximum solubility in FCC austenite at 1147 °C is 2.04 wt% 2.14 wt% 14.2 wt% O 0.022 wt% Oarrow_forwardFor a steel alloy it has been determined that a carburizing heat treatment of 16 h duration at 731°C will raise the carbon concentration to 0.40 wt% at a point 3.9 mm from the surface. Estimate the time necessary to achieve the same concentration at a 7.9 mm position for an identical steel and at a carburizing temperature of 1060°C. Assume that Do is 1.9 x 105 m²/s and Quis 108 kJ/mol, 3.89 -land Madin harrow_forward
- An FCC iron-carbon alloy initially containing 0.10 wt% C is carburized at an elevated temperature and in an atmosphere in which the surface carbon concentration is maintained at 1.10 wt%. If the treatment is conducted at 1050 °C, how long should the treatment be performed to reach a 0.30 wt% of carbon concentration at a position 4.2 mm below the surface?arrow_forwardAn FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere wherein the surface carbon concentration is maintained at 1.0 wt%. If after 51 h the concentration of carbon is 0.35 wt% at a position 3.5 mm below the surface, determine the temperature at which the treatment was carried out. You will need to use data in the two tables below to solve this problem. Diffusing Species Fe Table 5.1 Tabulation of Error Function Values erf(z) 0 0.0282 0.0564 0.1125 Fe Z 0 0.025 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 Table 5.2 A Tabulation of Diffusion Data Host Metal a-Fe (BCC) y-Fe (FCC) a-Fe 0.1680 0.2227 0.2763 0.3286 0.3794 y-Fe 0.4284 0.4755 0.5205 Z 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.0 1.1 1.2 Do(m²/s) 2.8 x 10-4 5.0 x 10-5 6.2 x 10-7 2.3 x 10-5 erf(z) 0.5633 0.6039 0.6420 0.6778 0.7112 0.7421 0.7707 0.7970 0.8209 0.8427 0.8802 0.9103 80 284 Z 1.3 1.4 1.5 1.6 1.7 1.8 1.9 Activation Energy Qa kJ/mol eVlatom 251…arrow_forwardIf the initial composition of the carbon steel is c0=0.3 wt%, calculate the carbon concentration (in wt%) at a distance 0.2mm from the surface of the component after 1 hour of decarburization.arrow_forward
- Determine the activation energy for vacancy formation in aluminum, if theequilibrium number of vacancies at 500 °C is 7.57 × 1023 m-3. Given that theatomic weight and density for aluminum are 26.98 g/mol and2.62 g/cm3, respectively.arrow_forwardGiven that a component is made of 0.1 wt.%C steel is carburized by introducing 1.0 wt.% carbon at its surface at 980ºC. Calculate the carbon content at 0.5 mm below the surface of this component after 1 hour.Do= 0.2 cm^2/s and Qd=40,000 cal/mol.arrow_forwardDecarburization of a steel occurs when carbon diffuses from the steel to the surface and enters the atmosphere. How long will it take for a 0.6 % C steel surface to decarburize below 0.1 % C for a depth of 2 mm if the FCC steel is held at 1250 °C in an atmosphere containing zero carbon? I need this question's answer. It's important for me.arrow_forward
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