EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Question
Chapter 5, Problem 5.8P
Interpretation Introduction
Interpretation:
Using ideal gas equation, the molar volume and the density of air in 40°C and a gauge pressure of 3 atm should be calculated.
Concept introduction:
The
Where, the volume (V) occupied by ‘n’ moles of any gas has a pressure (P) at temperature (T) in Kelvin and ‘R’ = Gas constant
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The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship
between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does:
|(V-nb) =nRT
The van der Waals equation of state. R stands for the gas constant and n for moles
of gas.
The parameters a and b must be determined for each gas from experimental data.
Use the van der Waals equation to answer the questions in the table below.
x10
What are the units of a?
What are the units of b?
For carbon dioxide the numerical value of a is 3.592 and the
numerical value of b is 0.0429.
Use the van der Waals equation to calculate the pressure of a
sample of carbon dioxide at 45.0 °C with a molar volume of
3.86 L/mol. Round your answer to the correct number of
significant digits.
atm
Use the Ideal Gas Law to calculate the pressure of the same
sample under the same conditions. Round your answer to the
correct number of significant digits.
atm
For a mixture of 0.0786 mol of C2H4 and 0.1214 mol of CO2 in a 700.0-cm3 container at 40°C, calculate the pressure using
(a) the ideal-gas equation; (b) the van der Waals equation, data in Table 8.1, and the C2H4 critical data Tc = 282.4 K, Pc =
49.7 atm; (c) the experimental compression factor Z = 0.9689.
Use the ideal gas law and Dalton’s law of partial pressures to prove that the mole fraction of gas A, XA, in a mixture of two gases, A and B, can be expressed as: XA = (nTRT)/VTPT - XB
Chapter 5 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
Ch. 5 - A liquid mixture containing 40.0 wt% n-octane and...Ch. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - A device has been designed to measure the flow...Ch. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - Spray drying is a process in which a liquid...Ch. 5 - Prob. 5.24PCh. 5 - Lewis12 describes the hazards of breathing air...Ch. 5 - A stream of air at 35°C and a gauge pressure of...Ch. 5 - Prob. 5.27PCh. 5 - In froth ?otation, air is bubbled through an...Ch. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Bread is typically made by ?rst dissolving...Ch. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - Prob. 5.34PCh. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - A spray-drying operation similar to that described...Ch. 5 - Prob. 5.41PCh. 5 - Fermentation is a biochemical process in which a...Ch. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Ethane at 25°C and 1.1 atm (abs) flowing at a rate...Ch. 5 - The ?ow of air to a gas-?red boiler furnace is...Ch. 5 - Prob. 5.47PCh. 5 - The oxidation of nitric oxide NO+12O2NO2 takes...Ch. 5 - Prob. 5.49PCh. 5 - 5.50.19 In chemical vapor deposition (CVD), a...Ch. 5 - A gas turbine power plant receives a shipment of...Ch. 5 - Prob. 5.52PCh. 5 - 5.53.20 Chemicals are stored in a laboratory with...Ch. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - A stream of ho dry nitrogen flows through a...Ch. 5 - Prob. 5.57PCh. 5 - You have purchased a gas cylinder that is supposed...Ch. 5 - The current global reliance on fossil fuels for...Ch. 5 - Two humid gas streams are combined in a heated...Ch. 5 - Most of the concrete used in the construction of...Ch. 5 - The ultimate analysis of a No. 4 fuel oil is 86.47...Ch. 5 - A stream of liquid n-pentane flows at a rate of...Ch. 5 - Alka-Seltzer( is an over-the-counter medicine used...Ch. 5 - Hydrogen sul?de has the distinctive unpleasant...Ch. 5 - The quantity of sulfuric acid used globally places...Ch. 5 - A small power plant produces 500 MW of electricity...Ch. 5 - You have been assigned the task of measuring the...Ch. 5 - Prob. 5.69PCh. 5 - Methanol is synthesized from carbon monoxide and...Ch. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Steam reforming is an important technology for...Ch. 5 - A ?owchart of a methanol synthesis process is...Ch. 5 - The measured volumetric flow rate of ethane at...Ch. 5 - Prob. 5.76PCh. 5 - Methanol is to be delivered to a process unit at a...Ch. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.80PCh. 5 - Prob. 5.81PCh. 5 - Prob. 5.82PCh. 5 - Prob. 5.83PCh. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - A fuel cell is an electrochemical device that...Ch. 5 - In a metered-dose inhaler (MDI), such as those...Ch. 5 - Prob. 5.92PCh. 5 - Prob. 5.93PCh. 5 - Approximately 150 SCFM (standard cubic feet per...Ch. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - The product gas from a coal gasification plant...Ch. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - A gas mixture consisting of 15.0 mole% methane....Ch. 5 - A system has been devised to store acetonitrile...Ch. 5 - Prob. 5.103PCh. 5 - Prob. 5.104P
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