Concept explainers
(a)
Interpretation:
The feed rates of the SO2 and air feed streams and the extent of reaction, e should be calculated.
Concept Introduction
The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.
(b)
Interpretation:
Calculate the standard heat of the SO2 oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.
Concept introduction:
The standard heat of formation will be helpful to solve the problem as:
(c)
Interpretation:
Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.
(d)
Interpretation:
The result if element species is taken into calculation in part (b) should be stated.
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Chapter 9 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
- 2. Ethanol is produced by the hydration of ethylene according to the first reaction below. However, some of the products are converted to diethyl ether according to the second reaction. C2H4 + H20 – C,H;0H 2C2H;OH - (C,H5)20 + H20 The feed to the reactor contains ethylene, steam, and N2 An effluent analysis is given in the following table: C2H4 Component %mol H2O 45.08 With a basis of 100 kmol of effluent, determine the following: CH;OH 2.95 (C2H5)20 0.27 N2 39.12 12.58 Determine the fractional yield of ethanol.arrow_forwardThe n-butane is converted into isobutane in an isomerization reactor, which operates isothermally at 149°C. Suppose that the reactor is fed with a mixture containing 93% mole of n-butane, 5% isobutane and 2% HCl at 149°C and that a 40% conversion of n-butane is achieved. How much heat in KJ/m3 (STP) of the feed, should be supplied or extracted from the reactor?arrow_forwardMethane is burned with air in a continuous combustion reactor that is at steady state.The feed to the reactor contains 7.80 mole % CH4, 19.4 mole % O2, and 72.8 mole % N4. The percentage conversion of methane is 90.0%, and the gas leaving the reactor contains 8 mol CO2/mol CO. Carry out a degree of freedom analysis of the process, and calculate the molar composition of the product stream.arrow_forward
- Your careless, clumsy lab mate has accidentally allowed carbon monoxide to leak out of a reactor, causing your lab’s CO monitor alarm to sound. After you quickly put on the appropriate Personal Protective Equipment, you find the leak and seal it. Then, you close your lab door, shut the windows, and call OSHA to report the hazard.When OSHA technicians arrive, they begin ventilating the 3000-ft3laboratory by pumping 25 ft3/min of fresh air into the room and removing the contaminated air at the same rate. They put a shop fan in the laboratory, such that the air is well-mixed. They also install a digital CO composition monitor, which currently reads 2 mol%. OSHA tells you that the laboratory is safe when there is less than 35 ppm of CO in the lab.How long must you wait to get back to work?arrow_forwardMethane (CH4) is reacted with oxygen (02) over a catalyst to produce acetlyene (C2H2) in the following reaction: 6 CHąlg) + O2lg) –→2 C2H2(g) + 2 CO(g) + 10 H2(g) If a feed containing 150 mol CHg and 50 mol O, is fed into a reactor and the conversion of the limiting reactant is 92 %, determine the concentration of CH, in the product flue gas. Give your answer as a mole percent rounded off to one decimal place.arrow_forward.edu bryuitra/courses roee_re Question Completion Status: The following process describes the complete combustion reaction of Toluene fuel C7HB (SG 0.866) with air. Liquid fuel (n1) enters the combustion chamber at 200mL/min, where it evaporated into a stream of air (n2) 15% in excess. Complete combustion reaction in which only fraction of the fuel is burned. The combustion products go to a condenser, where the unreacted fuel and water are liquified. The mass flowrate of the fuel in this steam (ma) is 50. The uncondensed gas leaves the condenser at 60 C and 0.5 atm gauge pressure. Calculate the fractional conversion of the fuel Calculate the SCMH of the air entering the combustion chamber Calculate the volumetric flow rate of the gas leaving the condenser (m³/min). a. b. C. ri4 CO2 n3 Fuel ris N2 Fuel ri1 ni4 CO2 nig O2 Combustion nig N2 Condenser air riz Chamber ng O2 ni, H,0 n3 Fuel niz H,0arrow_forward
- Two-hundred fifty pounds per hour of iron pyrites containing 90% FeS2 and 10% gangue are burned with 20% excess air based on conversion to SO3. The cinder discharged from the burner contains no sulfur. No conversion to SO3 occurs in the burner. The burner gas is passed through a converter which effects a 98% conversion of SO2 to SO3. The converter gas is passed to an absorber where all the SO3 is absorbed by 80% H2SO4 solution, which becomes 100% H2SO4 solution in the process. Establish a basis of one hundred pounds of iron pyrites Calculate: (a) the burner gas analysis, (b) the converter gas analysis, (c) pounds of 100% H2SO4 produced per 24-h day, if waste gas analyzes 0.19% SO2, 4.14% O2 and 95.67% N2arrow_forwardEthane is chlorinated in a continuous reactor: C2H6 + Cl2 à C2H5Cl + HCl Some of the product monochloroethane is further chlorinated in an undesired side relation: C2H5Cl + Cl2 à C2H4Cl2 + HCl Take a basis of 100 mol C2H5Cl produced. Assume that the feed contains only ethane and chlorine and that all of the chlorine is consumed and carry out a degree-of-freedom analysis based on atomic species balances. The reactor is designed to yield a 15% conversion of ethane and a selectivity of 14 mol C2H5Cl/mol C2H4Cl2. Calculate the feed ratio (mol Cl2/mol C2H6) and the fractional yield of monochloroethane.arrow_forwardThe synthesis of methanol from carbon monoxide and hydrogen is carried out in a continuous vapor-phase reactor at 5.00 atm absolute. The feed contains cO and H2 in stoichiometric proportion and enters the reactor at 25.0°C and 5.00 atm at a rate of 31.1 m³/h. The product stream emerges from the reactor at 157°C. The rate of heat transfer from the reactor is 21.0 kW. Calculate the fractional conversion (0 to 1) of carbon monoxide achieved and the volumetric flow rate (m3/h) of the product stream. f = Vout ! m3/harrow_forward
- 6- Floor beams of a transport airplane have been designed using an aluminum alloy containing 4.5 wt% Cu and 1.5 wt% Mg for a total weight of 95000 N. A customer has ordered the airplane but requested that its total weight be reduced by 10 percent for fuel saving purposes. An engineer in the design and analysis department has suggested that the weight saving objective can be accomplished by replacing the current aluminum alloy of the floor beams with another one containing 3 wt% Li and 1 wt% Cu. Is this possible? Answer the question by first determining the weight saving that will take place using the Al-Li alloy. Assume weighted averages of density and use the following densities for the mentioned materials: Al = 2.70 g/cm³ Cu = 8.92 g/cm³ Mg = 1.74 g/cm³ Li = 0.53 g/cm³arrow_forwardIn the combustion of heptane, CO, is produced. Assume that you want to produce 500 kg of dry ice per hour as shown in Fig. How many kilograms of heptane must be burned per hour? Other Products co, Solid 500 kg/hr Reactor C,H15 + 11 O2 7 CO, + 8 H;0 >arrow_forwardFigure below shows three reactors linked by pipes. As indicated, the rate of transfer of chemicals through each pipe is equal to a flow rate (Q, with units of cubic meters per second) multiplied by the concentration of the reactor from which the flow originates (c, with units of milligrams per cubic meter). If the system is at a steady-state, the transfer into each reactor will balance the transfer out. Develop mass-balance equations for the reactors and solve the three simultaneous linear algebraic equations for their concentrationsarrow_forward
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