Hybridization of central atom in tetrahedral geometry has to be determined. Concept Introduction: The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization. Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions. The table that relates hybridization with geometry and bond angles is as follows: Type of hybridization Number of lone pairs Molecular geometry Bond angles sp 0 Linear 180 ° sp 2 0 1 Trigonal planar Bent 120 ° sp 3 0 1 2 Tetrahedral Trigonal pyramidal Bent 109.5 ° sp 3 d 0 1 2 3 Trigonal Bi-pyramidal See-Saw T-shaped Linear 90 ° ,120 ° , 180 ° sp 3 d 2 0 1 2 Octahedral Square pyramidal Square planar 90 ° , 180 °

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Answer 1

Question

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

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Answer 2

Question

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 7

Chapter 2, Problem 2F.2E

(a)

Interpretation Introduction

Interpretation:

Hybridization of central atom in tetrahedral geometry has to be determined.

Concept Introduction:

The phenomenon of combination of atomic orbital of same atom to form hybrid orbitals of equivalent energies, shape or geometry is called hybridization.

Hybrid orbitals are formed by the mixture of atomic orbitals overlapped on each other of different proportions.

The table that relates hybridization with geometry and bond angles is as follows:

Type of hybridizationNumber of lone pairsMolecular geometryBond anglessp0Linear180 °sp201Trigonal planarBent120 °sp3012TetrahedralTrigonal pyramidalBent109.5 °sp3d0123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °sp3d2012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 8

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 2 - Prob. 2A.1AST Ch. 2 - Prob. 2A.1BST Ch. 2 - Prob. 2A.2AST Ch. 2 - Prob. 2A.2BST Ch. 2 - Prob. 2A.3AST Ch. 2 - Prob. 2A.3BST Ch. 2 - Prob. 2A.4AST Ch. 2 - Prob. 2A.4BST Ch. 2 - Prob. 2A.1E Ch. 2 - Prob. 2A.2E

Solution Summary: The author explains hybridization of central atom in tetrahedral geometry. Hybrid orbitals are formed by the mixture of atomic orbital overlapped on each other of different proportions.

Videos

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).

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Chapter 2 Solutions

Solution Summary: The author explains hybridization of central atom in tetrahedral geometry. Hybrid orbitals are formed by the mixture of atomic orbital overlapped on each other of different proportions.

Videos

Interpretation: Hybridization of central atom in trigonal bipyramidal geometry has to be determined. Concept Introduction: Refer to part (a).

Interpretation: Hybridization of central atom in octahedral geometry has to be determined. Concept Introduction: Refer to part (a).

Interpretation: Hybridization of central atom in linear geometry has to be determined. Concept Introduction: Refer to part (a).

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Chapter 2 Solutions

Interpretation:

Hybridization of central atom in trigonal bipyramidal geometry has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Hybridization of central atom in octahedral geometry has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Hybridization of central atom in linear geometry has to be determined.

Concept Introduction:

Refer to part (a).