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Concept explainers
(a)
Interpretation:
Condensed structural formula for propionyl chloride has to be drawn.
Concept Introduction:
General structure of acid chloride can be represented as shown below,
The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent
(b)
Interpretation:
Condensed structural formula for 3-methylbutanoyl chloride has to be drawn.
Concept Introduction:
General structure of acid chloride can be represented as shown below,
The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.
(c)
Interpretation:
Condensed structural formula for butyric anhydride has to be drawn.
Concept Introduction:
General structure of acid anhydride can be represented as shown below,
The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.
(d)
Interpretation:
Condensed structural formula for butanoic ethanoic anhydride has to be drawn.
Concept Introduction:
General structure of acid anhydride can be represented as shown below,
The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.
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Chapter 16 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
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- Determine the weight/volume of the chemicals needed to prepare the following solutions: a) 100 ml of 0.9% (w/v) saline (NaCl) b) 30 ml of 50% glycerol (v/v) c) Electrophoresis requires TAE, which is a specific mixture of Tris base, acetic acid, and EDTA. TAE is normally made as a 50X concentrated stock. Provide a recipe to make 40 ml of 50X TAE. The recipe for one liter of 50X TAE is as follows: 242g Tris base, 57.1 ml glacial acetic acid, 100 ml 0.5 M EDTAarrow_forwardللتدة Consider the following compounds. O 2 3 Use the numbers shown to answer the following questions. If none of the structures is applicable enter the word none. An anhydride is represented by the structure numbered O O HC 1 CH3 HC 3 CH3arrow_forwardScott test is one of the methods used for screening for Cocaine in Forensic Chemistry. The multi step method consists of a) reacting the sample drug with cobaltous thiocyanate (Co(SCN)2) b) dissolving of the formed precipitate by adding HCl and c) extraction of coordination compound with Chloroform d) measurement of absorbance of extracted coordination compound at 627 nm What is the type of chemical equilibria involved in first step of the method? a.Solubility Product equilibria b.Bronsted Lowry acid – Bronsted Lowry base equilibria c.Complex ion formation d.Coordination compound formationarrow_forward
- Complete the table for identification tests of amines and amides. What would be the composition/reagent used for: - Hinsberg - Quinhydrone - Ramini - Alkaline Hydrolysis - Acid Hydrolysis - Nitrous acid test What would be the Test for Amine/Amide for: - Hinsberg - Quinhydrone - Ramini - Alkaline Hydrolysis - Acid Hydrolysis - Nitrous acid test What would be the positive result for: - Hinsberg - Quinhydrone - Ramini - Alkaline Hydrolysis - Acid Hydrolysis - Nitrous acid testarrow_forwardMention at least two simple chemical tests by which you can distinguish between benzaldehyde and benzoic acid.arrow_forwardDraw all possible carboxylic acids with the formula C5H10O2.arrow_forward
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