Common name for the given ester has to be assigned. Concept Introduction: For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group. Rules to obtain IUPAC name and common name for an ester: Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word. Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group. Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”. To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Question

Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.) 1 СНО 2 СНО СНО Н-С—ОН Н-С—ОН Н—С—ОН Н-С—ОН НО —С—Н Н-С—ОН Н- С—ОН НО—С— Н НО—С—Н CH̟OH CH̟OH ČH̟OH в iоchemistry |61 STATE ATION Republic of the Philippines Romblon State University Romblan, Philippines 4 СНО 5 СНО 6 СНО НО—С—Н Н-С—ОН НО -С—Н Н—С—ОН НО -С—Н НО -С—Н H-C–OH Н-С—ОН НО—С—Н CH,OH ČH,OH CH,OH

Answer 1

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.) 1 СНО 2 СНО СНО Н-С—ОН Н-С—ОН Н—С—ОН Н-С—ОН НО —С—Н Н-С—ОН Н- С—ОН НО—С— Н НО—С—Н CH̟OH CH̟OH ČH̟OH в iоchemistry |61 STATE ATION Republic of the Philippines Romblon State University Romblan, Philippines 4 СНО 5 СНО 6 СНО НО—С—Н Н-С—ОН НО -С—Н Н—С—ОН НО -С—Н НО -С—Н H-C–OH Н-С—ОН НО—С—Н CH,OH ČH,OH CH,OH

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Which form of lysine in Problem 18.56 is the zwitterion? What is the pI for the zwitterion?

Answer 2

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 3

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 4

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 5

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 6

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 7

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 14

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Answer 15

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that an ester can be structurally viewed in a way that contains an acyl and an alkyl group.

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