EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Textbook Question
Chapter 6, Problem 6.2P
A quantity of methyl acetate is placed in an open, transparent, three-liter flask and boiled long enough to purge all air from the vapor space. The flask is then sealed and allowed to equilibrate at 30°C, at which temperature methyl acetate has a vapor pressure of 269 mm Hg. Visual inspection shows 10 mL of liquid methyl acetate present.
(a) What is the pressure in the flask at equilibrium? Explain your reasoning.
(b) What is the total mass (grams) of methyl acetate in the flask? What fraction is in the vapor phase at equilibrium?
(c) The above answers would be different if the species in the vessel were ethyl acetate because methyl acetate and ethyl acetate have different vapor pressures. Give a rationale for that difference.
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Students have asked these similar questions
Calculate the value of the equilibrium constant, Kc , for the reaction
Q(g)+X(g)↽−−⇀2M(g)+N(g)
given that
M(g)↽−−⇀Z(g)
Kc1=3.92
6R(g)↽−−⇀2N(g)+4Z(g)
Kc2=0.494
3X(g)+3Q(g)↽−−⇀9R(g)
Kc3=14.0
(a) Adsorption of a gas on surface of solid is generally accompanied by a decrease in entropy, still it is a spontaneous process. Explain.(b) Some substances can act both as colloids ’ and crystalloids. Explain.(c) What will be the charge on Agl colloidal particles when it is prepared by adding small amount of AgNO3 solution to KI solution in water ? What is responsible for the development of this charge ?
2) Based on the information below, determine the value of the unknown equilibrium constant, Kc.
2 NOCl (g) « 2 NO (g) + Cl2 (g)Kc = 2.4 x 10-7
1/3 Cl2 (g) + 2/3 NO (g) « 2/3 NOCl (g)Kc = ?
Chapter 6 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
Ch. 6 - Ten mL of pure liquid water in a cylinder with a...Ch. 6 - A quantity of methyl acetate is placed in an open,...Ch. 6 - Ethyl alcohol has a vapor pressure of 20.0 mm Hg...Ch. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.10P
Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Air at 50% relative humidity is cooled...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Air at 90°C and 1.00 atm (absolute) contains 10.0...Ch. 6 - When fermentation units are operated with high...Ch. 6 - When you step out of a shower, the temperature in...Ch. 6 - A fuel cell is an electrochemical device in which...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - An air conditioner is designed to bring 10.000...Ch. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - A gas stream containing 40.0 mole% hydrogen, 35.0%...Ch. 6 - Prob. 6.34PCh. 6 - In the manufacture of an active pharmaceutical...Ch. 6 - Prob. 6.36PCh. 6 - In the ?nal stage of the manufacturing process...Ch. 6 - Prob. 6.38PCh. 6 - A fuel gas containing methane and ethane is burned...Ch. 6 - A mixture of propane and butane is burned with...Ch. 6 - An important parameter in the design of gas...Ch. 6 - A liquid stream consisting of 12.5 mole% n-butane...Ch. 6 - Nitric acid is a chemical intermediate primarily...Ch. 6 - Prob. 6.44PCh. 6 - Sulfur trioxide (SO3) dissolves in and reacts with...Ch. 6 - State whether you would use Raoult’s law or Henrys...Ch. 6 - A gas containing nitrogen, benzene, and toluene is...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A conelation for methane solubility in...Ch. 6 - Prob. 6.51PCh. 6 - The constituent partial pressures of a gas in...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Nitrogen is bubbled through a liquid mixture that...Ch. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - The feed to a distillation column (sketched below)...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - A methanol-water feed stream is introduced to a...Ch. 6 - Prob. 6.72PCh. 6 - In this problem you will use a spreadsheet to...Ch. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Acetaldehyde is synthesized by the catalytic...Ch. 6 - Dehydration of natural gas is necessary to prevent...Ch. 6 - A two-unit process is used to separate H2S from a...Ch. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Prob. 6.83PCh. 6 - A solution containing 100 lbm KNO3/100 Ibm H2O at...Ch. 6 - A 10.0 wt% aqueous solution of sodium chloride is...Ch. 6 - Potassium dichromate (K2Cr2O7) is to be recovered...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Sodium bicarbonate is synthesized by reacting...Ch. 6 - An ore containing 90 wt% MgSO4(H2O and the balance...Ch. 6 - An aqueous waste stream leaving a process contains...Ch. 6 - A solution of diphenyl (MW = 154.2) in benzene is...Ch. 6 - An aqueous solution of urea (MW = 60.06) freezes...Ch. 6 - Prob. 6.94PCh. 6 - Derive Equation 6.54 for the boiling-point...Ch. 6 - Prob. 6.96PCh. 6 - A stream of 5.00 wt% oleic acid in cottonseed oil...Ch. 6 - Benzene and hexane are being considered as...Ch. 6 - Acetone is lo be extracted with n-hexane from a...Ch. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Five kilograms of a 30 wt% acetone70% water...Ch. 6 - An aqueous acetone solution is fed at a rate of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Air at 25°C and 1 atm with a relative humidity of...Ch. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Various amounts of activated carbon were added to...
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