EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 6, Problem 6.59P
Nitrogen is bubbled through a liquid mixture that initially contains equimolar amounts of benzene and toluene. The system pressure is 3 atm and the temperature is 80°C. The nitrogen flow rate is 10.0 standard liters per minute. The gas leaving the bubbler is saturated with benzene and toluene vapors.
(a) Estimate the initial rates (mol/min) at which benzene and toluene leave the bubbler.
(b) How will the mole fractions of benzene and toluene in the liquid change with time (increase. Decrease, or remain constant)? Explain your answer.
(c) How will the mole fractions of benzene and toluene in the exiting gas change with time (increase, decrease, or remain constant)? Explain your answer.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
P1A.6 The molar mass of a newly synthesized fluorocarbon was measured in a gas microbalance. is device consists of a glass bulb forming one end of a beam, the whole surrounded by a closed container. e beam is pivoted, and the balance point is attained by raising the pressure of gas
in the container, so increasing the buoyancy of the enclosed bulb. In one experiment, the balance point was reached when the fluorocarbon pressure was 327.10Torr; for the same setting of the pivot, a balance was reached when CHF3 (M = 70.014 g mol−1) was introduced at 423.22 Torr. A repeat of the experiment with a di erent setting of the pivot required a pressure of 293.22 Torr of the uorocarbon and 427.22 Torr of the CHF3. What is the molar mass of the fluorocarbon? Suggest a molecular formula.
Pressure
(A) Explain the term pressure and state its S.I. unit.
(B) Explain Henry’s law.
(C)A bottle of H2 has just been received by the technicians in DkIT for use in the instrumentation lab. It is a 47 litre cylinder at a pressure of 50 atmospheres. The normal working pressures is 2 bar. (i) To what volume of gas will that equate at the working pressure?
(ii) For how many hours will the gas last if it used at the rate of 0.5dm3 per hour?
D)You see your best friend at the bar and you walk up behind her. You accidentally startle her and she takes a step backwards. Unfortunately, she is wearing high heels and her heels come down on your foot. She weighs only 55kg but the size of her heel is 6mm by 6mm.Determine the pressure that she applies on your foot.
(E) If a diver dives to a depth of 35 m what will be: (i) the pressure in Pascals due the water column? (3 marks) (ii) the pressure of the air in…
An experiment on the growth rate of certain organisms requires an environment
of humid air enriched in oxygen. Three input streams are fed into an evaporation
chamber to produce an output stream with the following composition.
(A) Liquid water, fed at a rate of 20.0 cm³/min
(B) Air (21% mole % 02, the balance N2)
(C) Pure oxygen, with a molar flow rate one-fifth of the molar flow rate of
stream B
The output gas is analyzed and is found to contain 1.5 mole % water. Calculate
the molar flowrate of all unknown stream variables.
Chapter 6 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
Ch. 6 - Ten mL of pure liquid water in a cylinder with a...Ch. 6 - A quantity of methyl acetate is placed in an open,...Ch. 6 - Ethyl alcohol has a vapor pressure of 20.0 mm Hg...Ch. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.10P
Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Air at 50% relative humidity is cooled...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Air at 90°C and 1.00 atm (absolute) contains 10.0...Ch. 6 - When fermentation units are operated with high...Ch. 6 - When you step out of a shower, the temperature in...Ch. 6 - A fuel cell is an electrochemical device in which...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - An air conditioner is designed to bring 10.000...Ch. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - A gas stream containing 40.0 mole% hydrogen, 35.0%...Ch. 6 - Prob. 6.34PCh. 6 - In the manufacture of an active pharmaceutical...Ch. 6 - Prob. 6.36PCh. 6 - In the ?nal stage of the manufacturing process...Ch. 6 - Prob. 6.38PCh. 6 - A fuel gas containing methane and ethane is burned...Ch. 6 - A mixture of propane and butane is burned with...Ch. 6 - An important parameter in the design of gas...Ch. 6 - A liquid stream consisting of 12.5 mole% n-butane...Ch. 6 - Nitric acid is a chemical intermediate primarily...Ch. 6 - Prob. 6.44PCh. 6 - Sulfur trioxide (SO3) dissolves in and reacts with...Ch. 6 - State whether you would use Raoult’s law or Henrys...Ch. 6 - A gas containing nitrogen, benzene, and toluene is...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A conelation for methane solubility in...Ch. 6 - Prob. 6.51PCh. 6 - The constituent partial pressures of a gas in...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Nitrogen is bubbled through a liquid mixture that...Ch. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - The feed to a distillation column (sketched below)...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - A methanol-water feed stream is introduced to a...Ch. 6 - Prob. 6.72PCh. 6 - In this problem you will use a spreadsheet to...Ch. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Acetaldehyde is synthesized by the catalytic...Ch. 6 - Dehydration of natural gas is necessary to prevent...Ch. 6 - A two-unit process is used to separate H2S from a...Ch. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Prob. 6.83PCh. 6 - A solution containing 100 lbm KNO3/100 Ibm H2O at...Ch. 6 - A 10.0 wt% aqueous solution of sodium chloride is...Ch. 6 - Potassium dichromate (K2Cr2O7) is to be recovered...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Sodium bicarbonate is synthesized by reacting...Ch. 6 - An ore containing 90 wt% MgSO4(H2O and the balance...Ch. 6 - An aqueous waste stream leaving a process contains...Ch. 6 - A solution of diphenyl (MW = 154.2) in benzene is...Ch. 6 - An aqueous solution of urea (MW = 60.06) freezes...Ch. 6 - Prob. 6.94PCh. 6 - Derive Equation 6.54 for the boiling-point...Ch. 6 - Prob. 6.96PCh. 6 - A stream of 5.00 wt% oleic acid in cottonseed oil...Ch. 6 - Benzene and hexane are being considered as...Ch. 6 - Acetone is lo be extracted with n-hexane from a...Ch. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Five kilograms of a 30 wt% acetone70% water...Ch. 6 - An aqueous acetone solution is fed at a rate of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Air at 25°C and 1 atm with a relative humidity of...Ch. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Various amounts of activated carbon were added to...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Using PFE where required, find X(t) for a. X(s)=s(s+1)(s+2)(s+3)(s+4) b. X(s)=s+2( s+1)2 c. X(s)=1s2+s+1 d. X(s...
Process Dynamics and Control, 4e
Falsified Kinetics. The irreversible gas-phase dimerization
is carried out at 8.2 atm in a stirred contained-s...
Elements of Chemical Reaction Engineering (5th Edition) (Prentice Hall International Series in the Physical and Chemical Engineering Sciences)
Today, CPUs are huge devices made of electrical and mechanical components such as vacuum tubes and switches.
Starting Out with Python (3rd Edition)
T F If a file is opened in the definition of the file stream object, no mode flags may be specified.
Starting Out with C++ from Control Structures to Objects (8th Edition)
What is a source program?
Absolute Java (6th Edition)
Find Io in circuit in Fig. P2.110.
Basic Engineering Circuit Analysis
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 20. A mixture consisting of 6 kg of O, and 9 kg of N, has a pressure of 3 bar and temperature of 20°C. For the mixture determine the following : (i) The mole fraction of each component ; (iii) The specific gas constant; (v) The partial pressures and partial volumes. (ii) The average molecular weight ; (iv) The volume and density; [Ans. (i) 0.3684, 0.6315 ; (iüi) 29.475 ; (iii) 0.282 kJ/kg K ; (iv) 4.13 m?, 3.629 kg/m² ; (v) 1.1 bar, 1.894 bar ; 1.52 m², 2.61 m²)arrow_forward4.64. The gas-phase reaction between methanol and acetic acid to form methyl acetate and water CH;OH + CH3COOH = CH3COOCH3 + H2O (A) (В) (C) (D) takes place in a batch reactor. When the reaction mixture comes to equilibrium, the mole fractions of the four reactive species are related by the reaction eqilibrium constant Ky : = 4.87 YAYB (a) Suppose the feed to the reactor consists of n40,NB0, NCo, NDO, and no gram-moles of A, B, C, D, and an inert gas, I, respectively. Let į be the extent of reaction. Write expressions for the gram-moles of each reactive species in the final product, nA(2), nB(3), nc(E), and np(3). Then use these expressions and the given equilibrium constant to derive an equation for , the equilibrium extent of reaction, in terms of n20,.., N1o. (see Example 4.6-2.) (b) If the feed to the reactor contains equimolar quantities of methanol and acetic acid and no other species, calculate the equilibrium fractional conversion. (c) It is desired to produce 70 mol of methyl…arrow_forwardConsider the following reaction CS2(9) + 302(9) – CO2(9) + 2SO2(g) A mixture containing only CS2(g) and excess O2(g) at a total pressure of 100 kPa is placed in a sealed vessel. After the reaction is completed and the vessel is cooled to the initial temperature, the total pressure in the vessel drops to 80 kPa. What was the mole fraction of CS2(g) in the initial mixture? A. 0.80 B. 0.50 C. 0.20 D. 0.75 E. 0.25arrow_forward
- 3. (a) jf 10.0 mjL of H2jSO4 (sp. jr. 1.50, containing 48.7% of combined SO3 by weight) is diluted to 400 mL, what is the normality of the solution as an acid? (b) What volume of 6.00 M H2SO4 should be added to this in order to make the resulting mixture 1.00N as an acid? FW's : H2SO4 = 98; SO3 = 80 %3Darrow_forward+ |/ 00 %24 D. Two bulbs are connected by a stopcock. The 7.50 L bulb contains nitric oxide (NO) at a pressure of 0.340 bar, and the 2.50 L bulb contains oxygen (O,) at a pressure of 0.510 bar. 02 ON After the stopcock is opened, the gases mix and react to produce nitrogen dioxide (CON) 2 NO(g) + 0,(g) – 2 NO,(g) Considering that the volume remains unchanged during the experiment, how does the total pressure in the bulbs change if the reaction is allowed to go to completion? The total pressure will remain constant. O There is not enough information to determine how the total pressure will change. O The total pressure will decrease. O The total pressure will increase. MacBook Pro ( The %23 %24 7. 4. 5. 3. R %3D K. H. B C. option command MOSISOarrow_forwardA drum 6 inches in diameter and 40 inches long contained acetylene at 250 psia and 80°F. After some of the acetylene was used the pressure was 200 psia and the temperature was 70°F (a) what portion of the acetylene was used, and (b) what volume would the used acetylene occupy at 14.7 psia and 60°F. R(acetylene) = 59.35 ft-lbf/lbm-R Answer: a. b. V = % massarrow_forward
- The combustion gases from an industrial furnace using a hydrocarbon fuel and dry air enter the stack gas at normal barometric pressure and 3750F and have the following Orsat analysis: 12.2% CO2, 3.1% O2, 1.2% CO, and 83.5% N2. Determine the following: (a) The percent excess air (b) The volume of gases entering the stack, expressed as cubic feet per pound of carbon burnt in the furnace (c) The dew point of the stack gas (d) The atomic ratio of hydrogen to carbon in the fuel (e) The mol of stack gas per atom of carbon burntarrow_forwardIf a cylindrical tank holds 100,000 gallons of water, which can be drained from the bottom of the tank in an hour, then Torricelli's Law gives the volume V of water remaining in the tank after t minutes as 1 V (t) = 100, 000 (1- 60 for 0arrow_forward(a) Use the following data for NH3 (g) at T = 273 K to evaluate B2P (T). (Here Z is the compressibility factor, PV/RT). P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 0.70 Note: You will need to fit this data to a least-squares line. (b) At standard temperature (273.15 K), the density of O₂ varies with pressure as indicated in the table below: P (bar) 0.25331 0.50663 0.75994 1.01325 Z-1 1.519 x 10-4 3.038 x 10-4 4.557x 10-4 6.071 x 10-4 7.583 x 10-4 9.002 x 10-4 1.0551 x 10-3 2 p(g/L) 0.356985 0.714154 1.071485 1.428962 Use this data to find the second virial coefficient, B2v, of oxygen. Note that mo2 = 31.9988 Daltons. (Hint: It will be useful to determine the molar volume from each value of p.)arrow_forwardThe volume of HCI is 100 mL , mass of solid added is 1.008g, moles of solid 0.0276 Mol, mass of HCI is 100g, initial temperature is 21.8 degrees Celsius, Final temperature is 30.7 degrees Celsius, Calculate q rxn(= -mc Delta T of HCI),arrow_forwardP1A.5 Deduce the relation between the pressure and mass density, p, of a perfect gas of molar mass M. Confirm graphically, using the following data on methoxymethane (dimethyl ether) at 25°C, that perfect behaviour is reached at low pressures and find the molar mass of the gas. p/kPa 12.223 25.20 36.97 60.37 85.23 101.3 p/(kgm) 0.225 0.456 0.664 1.062 1.468 1.734arrow_forwardA steel cylinder containing compressed air is stored in a fermentation laboratory ready to provide aeration gas to a small-scale bioreactor. The capacity of the cylinder is 48 liters, the absolute pressure is 0.35 MPa and the temperature is 22°C. One day in mid-summer when the air conditioning breaks down, the temperature in the laboratory rises to 33°C and the valve at the top of the cylinder is accidentally left open. Estimate the proportion of air that will be lost.arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Mod-01 Lec-23 Degrees of freedom analysis; Author: nptelhrd;https://www.youtube.com/watch?v=c4h85JjrkzQ;License: Standard YouTube License, CC-BY
Introduction to Degrees of Freedom; Author: LearnChemE;https://www.youtube.com/watch?v=tW1ft4y5fQY;License: Standard Youtube License