Concept explainers
(a)
Interpretation:
Using given data construct a Txy diagram for the system.
Concept introduction:
Mass fraction is defined as the ratio of one component to the total mixture as,
Where, x = mass fraction,
(b)
Interpretation:
Estimate the mole fractions of acetone in the liquid and vapor phases for the given case.
Concept introduction:
Mass fraction is defined as the ratio of one component to the total mixture as,
Where, x = mass fraction,
(c)
Interpretation:
Estimate, the molar composition of each phase, the percentage of the total moles in the vessel and the percentage of vessel volume occupied by the vapor phase for the given case.
Concept introduction:
Mass fraction is defined as the ratio of one component to the total mixture as,
Where, x = mass fraction,
(d)
Interpretation:
Estimate the operating temperature of the evaporator and the compositions of the liquid and vapor product streams.
Concept introduction:
Mass fraction is defined as the ratio of one component to the total mixture as,
Where, x = mass fraction,
(e)
Interpretation:
Estimate the bubble-point temperature and vapor composition of the mixture.
Concept introduction:
Mass fraction is defined as the ratio of one component to the total mixture as,
Where, x = mass fraction,
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Chapter 6 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
- Thermodynamics and enthalpy Data: M(Pb) = 207 g mol" AmeltH°(Pb) = 4.8 kJ·mol" AvapH°(Pb) = 179.5 kJ·mol" Cp (Pb, liquid) = 32.4 J mol"' K-' Tmelt = 327°C Tvap = 1749°C Cp (Pb, solid) = 23.6 J mol·' K'' Let's consider the conversion of lead (Pb) in the gas phase at 1749 °C into lead in the solid state at 250 °C under the standard pressure P° = 1 bar. a. Calculate the standard molar enthalpy for this reaction.arrow_forwardIt is desired to determine the molecular weight of an organic compound known to be volatile. For this, a glass balloon with a full volume of 152 mL is weighed and the weighing result is recorded as 215 g. Then, the organic compound that is desired to have some molecular weight in liquid form is added into the balloon and evaporated in a water bath until dryness. After the steam temperature is measured as 90 °C, the balloon is left to cool and the organic compound in the balloon condenses again. The balloon is then weighed again and recorded as 215,367g. Find the molecular weight of this organic compound since the pressure of the environment where the experiment is performed is 700 mmHg.arrow_forwardQ1a-> A sample of hydrogen (H₂) gas was collected over water at 60°C. If the total volume of gas collected was 53.9 mL and the atmospheric pressure was 1.14 bar, what mass (in g) of hydrogen gas was collected above the water? The vapour pressure of water at 60°C is 150 torr. Q1b=> What is the molar mass (in g mol-¹) of a gas which has a density of 1.91 g/L at a pressure of 0.91 bar and temperature 15.3°C? Your answer may not correspond to an actual gas. Do not try to identify the gas.arrow_forward
- In a given industrial pipeline geared to the manufacture of a drug on a large scale, a pharmaceutical fluid (flowing into the pipeline) must be heated up to 80 °C by contact with boiling water circulating on the outside of the pipeline at the same temperature. At what pressure should we operate the heating line so that we have boiling water (water vapor in equilibrium with liquid water) at a temperature of 80 °C? It is known that water boils at 100 °C at atmospheric pressure (1 atm). Consider AvapH = +42.3 kJ / mol.arrow_forwardCalculate the solubility of nitrogen in water at an atmospheric pressure of 0.500 atm (a typical value at high altitude). Atmospheric Gas Mole Fraction kH mol/(L*atm) N2 7.81 x 10-1 6.70 x 10-4 O2 2.10 x 10-1 1.30 x 10-3 Ar 9.34 x 10-3 1.40 x 10-3 CO2 3.33 x 10-4 3.50 x 10-2 CH4 2.00 x 10-6 1.40 x 10-3 H2 5.00 x 10-7 7.80 x 10-4 Marrow_forwardThe table below shows temperature/composition data collected for a mixture of methylbenzene (M) and octane (O) at 1 atm. Recall that x stands for the mole fraction in the liquid and y stands for the mole fraction in the vapor in equilibrium. The boiling points for methylbenzene (M) and octane (O) are 110.60C and 125.60C, respectively. Construct the phase diagram with Temperature vs. xM. What is the composition of the vapor in equilibrium with the liquid of composition (a) xM = 0.250 and (b) xO = 0.250. T (0C) 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0 xM 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097 yM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164arrow_forward
- Calculate the solubility of hydrogen in water at an atmospheric pressure of 0.550 atm (a typical value at high altitude). Atmospheric Gas kH mol/(L*atm) Mole Fraction 7.81 x 101 2.10 x 101 9.34 x 103 3.33 х 104 2.00 x 10-6 5.00 x 107 N2 6.70 x 104 1.30 x 103 1.40 x 103 O2 Ar CO2 3.50 x 102 1.40 x 103 7.80 x 10-4 CH4 Н мarrow_forward1. Consider the temperature-composition diagram shown below for benzene (bp = 80°C) and toluene (bp = 110°C). For a 80/20 mixture of toluene to benzene answer the following: Temperature (°C) 110 8 95 90 3 80 1 T 1 1 0.2 0.4 0.6 Mole Fraction of Toluene a) At what temperature will the mixture begin to boil (use just approximate values)? b) When the mixture begins to boil, what is the mol % benzene in the vapor? c) What is the boiling point of the liquid formed by condensation of the vapor? 1 0.8 110 100 95 90 85 80arrow_forwardFatty acid mixtures can be used as drug release systems by taking advantage of the different thermal properties of the mixture when compared to those of the pure substances. A mixture of two fatty acids, myristic acid (MA) + stearic acid (SA), exhibits the following (experimentally determined) phase diagram. Sketch a cooling curve for 40% MA over the temperature range of 68 to 40 o Each time the slope of cooling curve changes, label the approximate temperature, as well as the components and phase (or phases) present in that region of the curve.arrow_forward
- Consider a system where 2.40 mol of CH3CN(g) are converted into CH3CN(1) at 1.00 atm and 82.0 °C. The normal boiling point of CH3CN is 82.0 °C, and AvapH much less than the volume of CH3CN(g). 29.75 kJ mol-1. Assume the volume of CH3CN(I) is What is the enthalpy change for the process described above? Enter your answer in kilojoules accurate to three significant figures. Do not use scientific/exponential notation. AH= Number kJ. What is the work done during the process described above? w= -7087.0 J w= 798.2 J w= -69.9 J w = 69.9 ) w = 7087.0 J O O Oarrow_forward• Complete this table for H₂O. T (°C) 220 P (kPa) 400 u (kJ/kg) 1450 Phase Saturated vaporarrow_forwardA fentanyl addict has spilled 1000 L of gasoline into the street (MW=117 g/mol, density=0.7 g/mL). In response, firefighters disperse 54×103 kg of a material into the gasoline and reduced its vapor pressure from the pure partial pressure of 24 kPa (about ¼ an atm) down to 2.4 kPa. They do this because liquid gas doesn’t burn, just the vapors. What is the molecular weight of the material that was added? (hint: use Raoult’s Law, which relates changes in pressure to the mol fractions.)arrow_forward
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