Concept explainers
(a)
Interpretation:
A flowchart for the given process is to be drawn and labelled. The validation of the given statement that subsystem containing the point where the bypass stream splits off from the evaporator feed has one degree of freedom is to be stated. The degree of freedom analysis for the overall system, the evaporator, bypass-evaporator product and the mixing point is to be predicted. The equations to determine all unknown stream variable are to be shown. The variable in each equation is to be circled.
Concept introduction:
The evaporation is a process that aids in the conversion of a liquid into gas due to rise in temperature. The process of evaporation becomes faster with the increase in surface area because it permits the liquid molecules to acquire more heat. It results in the increase in kinetic energy of molecules, which aids to overcome of attractive forces between molecules of liquid.
In reverse osmosis, the solvent passes in the opposite direction to that of osmosis.
(b)
Interpretation:
The amount of product produced per
Concept introduction:
The evaporation is a process that aids in the conversion of a liquid into gas due to rise in temperature. The process of evaporation becomes faster with the increase in surface area because it permits the liquid molecules to acquire more heat. It results in the increase in kinetic energy of molecules, which aids to overcome of attractive forces between molecules of liquid.
In reverse osmosis, the solvent passes in the opposite direction to that of osmosis.
(c)
Interpretation:
The possible drawbacks for the given proposal are to be stated.
Concept introduction:
The evaporation is a process that aids in the conversion of a liquid into gas due to rise in temperature. The process of evaporation becomes faster with the increase in surface area because it permits the liquid molecules to acquire more heat. It results in the increase in kinetic energy of molecules, which aids to overcome of attractive forces between molecules of liquid.
In reverse osmosis, the solvent passes in the opposite direction to that of osmosis.
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Chapter 4 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
- A student performs a crystallization on an impure sample of biphenyl. The sample weighs 0.5 g and contains about 5% impurity. Based on his knowledge of solubility, the student decides to use benzene as the solvent. After crystallization, the crystals are dried and the nal weight is found to be 0.02 g. Assume that all steps in the crystallization are performed correctly, there are no spills, and the student lost very little solid on any glassware or in any of the transfers. Why is the recovery so low?arrow_forward5.0 mL of 1-butanol was mixed with 10 mL of HCl. The reaction was put on an ice bath and 4 mL of concentrated sulfuric acid was added. This mixture was refluxed for 45 min and then the product was co-distilled with water using a simple distillation apparatus. Water and the product are immiscible. 1-butanol has a molar mass of 74.12 g/mol, a density of 0.810 g/mL, and a boiling point of 118 C. The product has a molar mass of 92.57 g/mol, a density of 0.880 g/mL, and a boiling point of 78 C. What is the nucleophile in this reaction? What is the role of H2SO4 in this reaction? Calculate the theoretical yield for this reaction. Give your answer in grams. Select the following statements that can be said about the reaction shown.arrow_forwardAn organic chemistry student isolates 738 mg of salicylic acid (SA) and decides to use methanol in an attempt to purify it by recrystallization. Use the following information to calculate the maximum amount (in mg) that can purified from the crude product. SA solubility in methanol: o°C = 41.3 g/100 mL 56 °C = 64.5 g/100 mLarrow_forward
- A sample (50 mL) of a bottled water was added to a 100 mL volumetric flask and then diluted to the mark. From this stock solution, 50 mL was taken, added to a 100 mL volumetric flask and diluted to the mark. Final concentration of the serial dilution: 587.7161ppm. 1. what is the concentration in the original bottle (ppm)arrow_forwardYou carry out an experiment on the physical properties of 3 organic compounds and observe the following data: Substance Solubility in Water medium Compound A low Compound B high Compound C You know that the 3 organic compounds are an alkene, ketone and alcohol of equal hydrocarbon length. Match the compounds above to their specific organic compound type based upon their solubility. And give a structural reason for the solubility observations that are observed. (I:3) Substance Identity Reason Compound A Compound B Compound Carrow_forwardHow to prepare the solutions listed below Solution 1) 25 mL 7 M sulfuric acid and the respective dilution of this solution to prepare 50 mL 2 M sulfuric acid in deionised water. Sulfuric acid Mw = 98.079 g mol-1 Sulfuric acid density = 1.84 g mL-1 Sulfuric acid purity = 98% Solution 2) 100 mL 0.02M potassium permanganate potassium permanganate Mw = 158.03 g mol-1 potassium permanganate purity = 99%arrow_forward
- The followings methods are useful to induce crystallization EXCEPT adding a small crystal of the desired compound, called a seed crystal, to the solution adding anhydrous potassium carbonate to the solution and cooling it in an ice bath scratching the inner wall of the Erlenmeyer flask with a glass stirring rod reheating the solution to boiling to boil off some of the solvent, and then allow the solution to cool to room temperature again to effect crystallizationarrow_forwardA bucket has 100 m3 of air, 60 m3 of water and 3 m3 of sediment. You add 2 mol of benzene to the water in the bucket. 1) Draw a conceptual model of this system. 2) Using arrows or some other symbols, identify what will happen to the benzene at equilibrium. Write the mass balance for this. Is it open or closed? Write the mass balance for an open system. What is fugacity used for? What is the difference between steady state and equilibrium?arrow_forwardb) Will the sample be contaminated with any of the impurities? Calculate the percent purity of the initial sample (in terms of compound A) - ( i.e. express the amount of compound A in the initial sample as a percentage of the mass of initial sample). Calculate the percent purity of the final sample (in terms of compound A) - (i.e. express the amount of compound A in the final sample as a percentage of the mass of final sample). Did the recrystallization procedure result in an increase of the percent purity of compound A in the sample? Comment on the results.arrow_forward
- 1)Please express the normal salt (NaCl) concentration in body fluid into molarity (mM).2) Commercial fuming Sulphuric acid (Oleum-H2S2O6) is 99.9%. solution. Please convert it into molarity.3) Find out the Volume (dm3) of product (gas) at RTP when 0.58 M, 150 mL NaOH (aq.) reacts with 350 mL, 0.25 NH4Cl.4) The above reaction has the product Ammonia, which when dissolved in 650 mL ethanol makes an alkaline ethanolic solution. Find its molarity (M) 5) Calculate the adult dose as per the BW of the baby. (Child dose-50 mg and the BW of the baby is 48 lb (British pound) (1lb=0.453 Kg)arrow_forwardFour students are investigating how temperature affects solubility rates of different solutes in water. After preparing their own saturated solutions at 50 ⁰C, they allowed them to cool down to 25 ⁰C. Saturated Solutions in Water Student Solute Temperature ⁰C Quantity Dissolved (g/100 g H2O) Amber LiCl 25 82 50 97 James KCl 25 36 50 44 Rachel NaCl 25 35 50 37 Timothy C12H22O11 25 103 50 130 Analyzing the results of their investigation, how would you rank the students with the quantity of grams that came out of their solutions from GREATEST to LEAST? A James > Rachel > Timothy > Amber B Amber > James > Timothy > Rachel C Timothy > Amber > James > Rachel D Rachel > James > Amber > Timothyarrow_forwardYou have an aqueous solution of pyridinium chloride (C6H5N'HCI) and you want to extract it with a second solvent where it would be more soluble. Which of the following should you do to accomplish the said task? Mix 3M NaOH, acetone, and the aqueous layer in a separatory funnel, shake, release build-up pressure, return to A stand, and let the mixture separate into two layers. Mix methanol and the aqueous layer in a separatory funnel, shake, release build-up pressure, return to stand, and let the mixture separate into two layers. Mix 3M NaOH, toluene, and the aqueous layer in a separatory funnel, shake, release build-up pressure, return to stand, and let the mixture separate into two layers. Mix dichloromethane and the aqueous layer in a separatory funnel, shake, release build-up pressure, return to stand, D and let the mixture separate into two layers.arrow_forward
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