EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Chapter 4, Problem 4.71P

Solid calcium fluoride (CaF2) reacts with sulfuric acid to form solid calcium sulfate and gaseous hydrogen fluoride (HF). The HF is then dissolved in water to form hydrofluoric acid. A source of calcium fluoride is fluorite ore containing 96.0 wt% CaF2 and 4 .OS? SiO2.

In a typical hydrofluoric acid manufacturing process, fluorite ore is reacted with 93 wtS? aqueous sulfuric acid, supplied 15% in excess of the stoichiometric amount. Ninety-five percent of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction

6HF + SiO2(aq) -» H2SiF6(s) + 2H2O(1)

The hydrogen fluoride exiting from the reactor is subsequently dissolved in enough water to produce 60.0 wtS? hydrofluoric acid. Calculate the quantity of fluorite ore needed to produce a metric ton of aqueous hydrofluoric acid. Note: Some of the given data are not needed to solve the problem.

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Chapter 4 Solutions

EBK ELEMENTARY PRINCIPLES OF CHEMICAL P

Ch. 4 - In the production of soybean oil, dried and flaked...Ch. 4 - Prob. 4.12PCh. 4 - A process is carried out in which a mixture...Ch. 4 - Strawberries contain about 15wt% solids and 85wt%...Ch. 4 - Two streams flow into a 500-gallon tank. The first...Ch. 4 - A fuel distributor supplies four liquid fuels,...Ch. 4 - Prob. 4.17PCh. 4 - One thousand kilograms per hour of a mixture...Ch. 4 - L-Serine is an amino acid that often is provided...Ch. 4 - A 100 kmol/h stream that is 97 mole% carbon...Ch. 4 - A pharmaceutical product, P, is made in a batch...Ch. 4 - A liquid mixture containing ethanol (55.0 wt%) and...Ch. 4 - A stream of humid air containing 1.50 mole% H2O(v)...Ch. 4 - A liquid mixture contains 60.0 wt% ethanol (E),...Ch. 4 - Certain vegetables and fruits contain plant...Ch. 4 - Two aqueous sulfuric acid solutions containing...Ch. 4 - A paint mixture containing 25.0% of a pigment and...Ch. 4 - In the commercial production of sugar (sucrose),...Ch. 4 - Prob. 4.29PCh. 4 - A garment to protect the wearer from toxic agents...Ch. 4 - A dilute aqueous solution of H2SO4 (Solution A) is...Ch. 4 - Gas streams containing hydrogen and nitrogen in...Ch. 4 - An artificial kidney is a device that removes...Ch. 4 - The indicator-dilution method is a technique used...Ch. 4 - Prob. 4.35PCh. 4 - Gas absorption or gas scrubbing is a commonly used...Ch. 4 - The SO2 scrubbing tower described in Problem 4.36...Ch. 4 - Prob. 4.38PCh. 4 - The hormone estrogen is produced in the ovaries of...Ch. 4 - A liquid mixture containing 30.0mole% benzene (B),...Ch. 4 - Seawater containing 3.50 wt% salt passes through a...Ch. 4 - Inside the column a liquid stream flows downward...Ch. 4 - Prob. 4.43PCh. 4 - Effluents from metal-finishing plants have the...Ch. 4 - In an absorption tower (or absorber), a gas is...Ch. 4 - In the production of a bean oil, beans containing...Ch. 4 - Boilers are used in most chemical plants to...Ch. 4 - Following is a diagram of the shirt-cleaning...Ch. 4 - A drug (D) is produced in a three-stage extraction...Ch. 4 - Prob. 4.52PCh. 4 - Ammonia is oxidized to nitric oxide in the...Ch. 4 - Prob. 4.54PCh. 4 - A stream containing H2S and inert gases and a...Ch. 4 - 436. The reaction between ethylene and hydrogen...Ch. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - Titanium dioxide (TiCb) is used extensively as a...Ch. 4 - Prob. 4.60PCh. 4 - Prob. 4.61PCh. 4 - Oxygen consumed by a living organism in aerobic...Ch. 4 - A genetically engineered strain of Escherichia...Ch. 4 - The gas-phase reaction between methanol and acetic...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Methane and oxygen react in the presence of a...Ch. 4 - Ethane is chlorinated in a continuous reactor:...Ch. 4 - Ethanol can be produced commercially by the...Ch. 4 - Prob. 4.70PCh. 4 - Solid calcium fluoride (CaF2) reacts with sulfuric...Ch. 4 - Prob. 4.72PCh. 4 - Chlorobenzene (C^HsCl), an important solvent and...Ch. 4 - A catalytic reactor is used to produce...Ch. 4 - 4.7'6. Methanol is produced by reacting carbon...Ch. 4 - Methane reacts with chlorine to produce methyl...Ch. 4 - Ethylene oxide is produced by the catalytic...Ch. 4 - Methanol is synthesized from carbon monoxide and...Ch. 4 - The fresh feed to an ammonia production process...Ch. 4 - A gas contains 75.0 wt% methane. 10.0% ethane....Ch. 4 - Five liters of liquid n-hexane and 4 liters of...Ch. 4 - Gasoline, which we will represent as having the...Ch. 4 - Prob. 4.87PCh. 4 - Natural gas containing a mixture of methane,...Ch. 4 - Propane is burned completely with excess oxygen....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Liquid methanol is fed to a space heater at a rate...Ch. 4 - Prob. 4.94PCh. 4 - Prob. 4.95PCh. 4 - A fuel oil is analyzed and found to contain 85.0...Ch. 4 - Prob. 4.97PCh. 4 - Prob. 4.98PCh. 4 - Prob. 4.99PCh. 4 - 4.1 (Mt. You have been sent by the Environmental...Ch. 4 - Fuel oils contain primarily organic compounds and...

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