Concept explainers
(a)
Interpretation:
Draw a flowchart for the catalytic dehydrogenation of propane from the description of this process that begins section 4.3a. Label all feed, product, and connecting streams between units.
Concept introduction:
When a few process information is given and the calculation is to be done on the basis of the information, then in such conditions, flowchart creation is the best way to deal with. It is formed with the help of boxes and arrows to show the process and outline the process units. The arrow lines can show inputs and outputs which help in better understanding of the process.
(b)
Interpretation:
Write clear statements of the overall objective of the process and the functions of each of the process units (the preheater, the reactor, the absorption and stripping towers and the distillation column).
Concept introduction:
When a few process information is given and the calculation is to be done on the basis of the information, then in such conditions, flowchart creation is the best way to deal with. It is formed with the help of boxes and arrows to show the process and outline the process units. The arrow lines can show inputs and outputs which help in better understanding of the process.
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Chapter 4 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
- Here is a use objective for a chemical analysis to be performed at a drinking water purification plant: “Data and results collected quarterly shall be used to determine whether the concentrations of haloacetates in the treated water demonstrate compliance with the levels set by the Stage 1 Disinfection By-products Rule using Method 552.2” (a specification that sets precision, accuracy, and other requirements). Which one of the following questions best summarizes the meaning of the use objective?(i) Are haloacetate concentrations known within specified precision and accuracy?(ii) Are any haloacetates detectable in the water?(iii) Do any haloacetate concentrations exceed the regulatory limit?arrow_forward(3) Below are five depictions of a column at various points throughout the loading/ packing process. [a] alumina pet. ether alumina sand cotton [b] pet. ether alumina sand cotton [C] pet. ether sand cotton [d] pet. ether 50:50 fluorenone ferrocene alumina sand cotton (a) Place these depictions in correct chronological order according to the procedure. [e] pet. ether sand 50:50 fluorenone ferrocene alumina sand cotton (b) Consider the set-up in depiction [a]. What technique-related skill can the student do to resolve this error? Explain in 10 words or less. (c) Consider the set-up in depiction [b]. What should the student do at this point? What are the consequences of not monitoring this step carefully? Explain with 20 words or fewer.arrow_forward2) A) What mass of air is required to burn 1.0 kg of ethylene to completion. (stoichiometric) B) What mass of air is required to burn 1.0 kg of ethylene to completion with 15% excess air.arrow_forward
- 2. In an ethanol production plant, a separator produces a 99% ethanol product from a feedstock stream containing 85% water and 15% ethanol at a rate of 450 Ib/min. The separator has two outlet streams: the ethanol product outlet stream (99% ethanol) and a residual water stream. 30% of the feedstock is bypassed and mixed with the residual water stream leaving the separator. If 60% of the ethanol entering the separator is recovered in the product stream, determine the composition of the residual water stream just after leaving the separator and the composition of the residual stream after mixing with the bypass stream.arrow_forward6. A volatilization gravimetry experiment was conducted on an unknown organic liquid (presumed to only contain carbon, hydrogen, and oxygen). The liquid was massed (data in the first column below) and then combusted in an excess of oxygen. The exhaust gas was passed through a trap containing drierite and then through a trap containing ascarite. The starting and ending masses of the drierite and ascarite were used to obtain the data in the second two columns below. Mass Unknown 12.4370 12.5590 12.2230 Mass CO2 17.0822 17.2497 16.7882 Mass H₂O 13.9849 14.1221 13.7443 A.) Calculate the mass percent of carbon, hydrogen, and oxygen in the unknown liquid. There are no outliers, so you can average the data before processing, if you wish. B.) Calculate the empirical formula of the unknown compound.arrow_forwardAlka-Seltzer is marketed as a remedy for stomach problems, such as heartburn or indigestion, and pain relief. It contains aspirin, sodium bicarbonate, and citric acid, and is effervescent when placed in water. Enter the equation for the reaction of one sodium bicarbonate (NaHCO,) molecule with one citric acid (C,H,0,) molecule. Do not include phases. equation: 3H, CO, + C,H;O,Na, 3H,0 + 3CO, + C,H,O,Na; Incorrectarrow_forward
- Feed gas containing of 78.5mol % H₂, 21% of N₂ & 0.5% of Ar is mixed with recycle gas and enters a reactor where 15% N₂ is converted to NH3 as per the reaction. Ammonia from the exit of the reactor is completely separated from unconverted gases. To avoid the buildup of inerts, a small fraction (5%) of the unreacted gases purged and the balance recycled. USING ASPEN/HYSYS Draw the process flow sheet Product rate and Purge rate Basis:100mol/hrarrow_forward5. (a) A polymer sample was analysed by differential scanning calorimetry and the thermogram shown in the figure below was obtained. Highlight and describe the key thermal transitions occurring in this sample. ^ 2 EXOTHERMIC (b) From the reactivity ratio data for the free-radical copolymerisations shown below, state what class of polymer is produced from these reactions and justify your answer. Reaction Monomer 1 1 Styrene Styrene Methyl Methacrylate Ethylene 3 50 Temperature 4 Monomer 2 Methyl Methacrylate Vinyl acetate Vinyl chloride Vinyl acetate Temp./°C r₁ 12 60 60 100 68 130 0.52 0.46 55 0.01 10 0.1 0.97 1.02arrow_forwardUse E5C.1(a) to Plot the data in excel. Place two data sets on the same graph: one for temp vs. x and one for temp vs y (remember, x and y are the mole fractions and they belong on the x-axis). Don’t forget to include the boiling points of the pure substances – they are data, too. Add a trendline (polynomial, 3rd order should work) to each of the coexistence lines separately. Scale the plot appropriately and use the graph to answer the questions. Then complete E5C.1(b)arrow_forward
- 2. Ethanol is produced by the hydration of ethylene according to the first reaction below. However, some of the products are converted to diethyl ether according to the second reaction. C2H4 + H20 – C,H;0H 2C2H;OH - (C,H5)20 + H20 The feed to the reactor contains ethylene, steam, and N2 An effluent analysis is given in the following table: C2H4 Component %mol H2O 45.08 With a basis of 100 kmol of effluent, determine the following: CH;OH 2.95 (C2H5)20 0.27 N2 39.12 12.58 Determine the fractional yield of ethanol.arrow_forward6. Two units of non-atomic traffic travel from start to end in the selfish routing network shown below. There are three paths. (a) Find the equilibrium flow and cost. (b) Find the optimal flow and cost and use this and your answer in part (a) to calculate the POA.arrow_forwardTotal Suspended Solids Dried at 105°C Table 2.2: Preparing clean and dry filter paper: Finalized filter paper weight (g) Filtrating the water sample: Empty dish + Clean filter paper weight (g) Sample volume (mL) Empty dish + filter paper with dried residue weight (g) Total suspended Solids (mg Total Suspended Solids /L) (Round to zero decimal point) Set 1 0.2458 Set 1 37.8186 10 38.0628 24420 Average (Round to zero decimal point) Precision check (Round to four decimal point) Use the formula below to find the precision check Set 2 0.2458 Set 2 37.8186 10 38.0628 24420 24420 Precision: Check precision whether agree within 5% of their sum using following equation: [](1st sample result – 2nd sample result) | / sum of 1st and 2nd sample] x 100 < 5arrow_forward
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